Synthesis of Lariat Ethers Containing Sulfur Donor Atoms in the Side Arms

Chem. J. Chinese Universities ›› 1994, Vol. 15 ›› Issue (8): 1159.

• Articles • Previous Articles Next Articles

Synthesis of Lariat Ethers Containing Sulfur Donor Atoms in the Side Arms

WANG De-Fen, YU Jun-Biao, Hu Jia-Xin, JIANG Yan-Hao, HU Hong-Wen

Department of Chemistry and Chemical Engineering, Nanjing University, Nanjing, 210008

Received:1993-08-22 Revised:1994-02-03 Online:1994-08-24 Published:1994-08-24

Abstract

Abstract: Five new bibracchial lariat Ethers(double armed diaza crown ethers)containing sulfur donor atoms in the side arms were synthesized in 37%─72%yield by treating the acetonitrile solution of diaza-18-crown-6 with 2-chloroethyl alkyl sulfide, 2-chloro allyl sulfide, [2-(2-chloroethyl)thioethyl]alkyl sulfide in the presence of anhydrous sodium carbonate.The corresponding lariat ethers(single armed diaza crown ethers) were obtained simutaneously in 13%─37%yield. Therefore this is a facile method for the synthesis of single armed diaza crown ethers.

Key words: Bibracchial lariat ethers, Sulfur, Alkylation, Synthesis

TrendMD:

WANG De-Fen, YU Jun-Biao, Hu Jia-Xin, JIANG Yan-Hao, HU Hong-Wen. Synthesis of Lariat Ethers Containing Sulfur Donor Atoms in the Side Arms[J]. Chem. J. Chinese Universities, 1994, 15(8): 1159.

[1]	CAO Shujie, LI Hongjun, GUAN Wenli, REN Mengtian, ZHOU Chuanzheng. Progress on the Stereocontrolled Synthesis of Phosphorothioate Oligonucleotides [J]. Chem. J. Chinese Universities, 2022, 43(Album-4): 20220304.
[2]	WANG Ruyue, WEI Hehe, HUANG Kai, WU Hui. Freezing Synthesis for Single Atom Materials [J]. Chem. J. Chinese Universities, 2022, 43(9): 20220428.
[3]	YAO Qing, YU Zhiyong, HUANG Xiaoqing. Progress in Synthesis and Energy-related Electrocatalysis of Single-atom Catalysts [J]. Chem. J. Chinese Universities, 2022, 43(9): 20220323.
[4]	WEI Chunhong, JIANG Qian, WANG Panpan, JIANG Chengfa, LIU Yuefeng. Atomic Scale Investigation of Pt Atoms/clusters Promoted Co-catalyzed Fischer-Tropsch Synthesis [J]. Chem. J. Chinese Universities, 2022, 43(8): 20220074.
[5]	JIN Ruiming, MU Xiaoqing, XU Yan. Bio-chemical Synthesis of Melanin Precursor—— 5，6-Dihydroxyindole（DHI） [J]. Chem. J. Chinese Universities, 2022, 43(8): 20220134.
[6]	ZHANG Xinxin, XU Di, WANG Yanqiu, HONG Xinlin, LIU Guoliang, YANG Hengquan. Effect of Mn Promoter on CuFe-based Catalysts for CO₂ Hydrogenation to Higher Alcohols [J]. Chem. J. Chinese Universities, 2022, 43(7): 20220187.
[7]	ZHOU Zixuan, YANG Haiyan, SUN Yuhan, GAO Peng. Recent Progress in Heterogeneous Catalysts for the Hydrogenation of Carbon Dioxide to Methanol [J]. Chem. J. Chinese Universities, 2022, 43(7): 20220235.
[8]	LI Yidi, TIAN Xiaochun, LI Junpeng, CHEN Lixiang, ZHAO Feng. Electron Transfer on the Semiconductor-microbe Interface and Its Environmental Application [J]. Chem. J. Chinese Universities, 2022, 43(6): 20220089.
[9]	LU Cong, LI Zhenhua, LIU Jinlu, HUA Jia, LI Guanghua, SHI Zhan, FENG Shouhua. Synthesis， Structure and Fluorescence Detection Properties of a New Lanthanide Metal-Organic Framework Material [J]. Chem. J. Chinese Universities, 2022, 43(6): 20220037.
[10]	CHEN Weiqin, LYU Jiamin, YU Shen, LIU Zhan, LI Xiaoyun, CHEN Lihua, SU Baolian. Preparation of Organic Hybrid Mesoporous Beta Zeolite for Alkylation of Mesitylene with Benzyl Alcohol [J]. Chem. J. Chinese Universities, 2022, 43(6): 20220086.
[11]	ZHUANG Jiahao, WANG Dingsheng. Current Advances and Future Challenges of Single-atom Catalysis [J]. Chem. J. Chinese Universities, 2022, 43(5): 20220043.
[12]	YIN Xiaoju, SUN Xun, ZHAO Chenghao, JIANG Bo, ZHAO Chenyang, ZHANG Naiqing. Research Progress of Single Atomic Catalysts in Lithium-sulfur Batteries [J]. Chem. J. Chinese Universities, 2022, 43(5): 20220076.
[13]	FENG Li, SHAO Lanxing, LI Sijun, QUAN Wenxuan, ZHUANG Jinliang. Synthesis of Ultrathin Sm-MOF Nanosheets and Their Visible-light Induced Photodegradation of Mustard Simulant [J]. Chem. J. Chinese Universities, 2022, 43(4): 20210867.
[14]	MENG Xianglong, YANG Ge, GUO Hailing, LIU Chenguang, CHAI Yongming, WANG Chunzheng, GUO Yongmei. Synthesis of Nano-zeolite and Its Adsorption Performance for Hydrogen Sulfide [J]. Chem. J. Chinese Universities, 2022, 43(3): 20210687.
[15]	ZHANG Shiyu, HE Runhe, LI Yongbing, WEI Shijun, ZHANG Xingxiang. Fabrication of Lithium-sulfur Battery Cathode with Radiation Crosslinked Low Molecular Weight of Polyacrylonitrile and the Mechanism of Sulfur Storage [J]. Chem. J. Chinese Universities, 2022, 43(3): 20210632.

Synthesis of Lariat Ethers Containing Sulfur Donor Atoms in the Side Arms

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments