Linear Free Energy Relationship of Complexes(ⅩⅤⅡ)──Studies on the Stability of Copper(Ⅱ)-Dioxotetraamine Macrocycles-α-Aminoacids Ternary Complexes

Chem. J. Chinese Universities ›› 1994, Vol. 15 ›› Issue (2): 163.

• Articles • Previous Articles Next Articles

Linear Free Energy Relationship of Complexes(ⅩⅤⅡ)──Studies on the Stability of Copper(Ⅱ)-Dioxotetraamine Macrocycles-α-Aminoacids Ternary Complexes

XIAN Jing-Chun, ZHU Shou-Rong, LIN Hua-Kuan, CHEN Rong-Ti

Department of Chemistry, Nankai University, Tianjin, 300071

Received:1993-04-12 Revised:1993-06-20 Online:1994-02-24 Published:1994-02-24

Abstract

Abstract: The stability of Cu( Ⅱ)-12-(2'-hydroxy-5- substituted benzyl) - 1,4,7, 10- tetraazacyclotridecane-11, 13-dione-a-aminoacids ternary systems has been studied by pHtitration method at 25.0±0.1℃and I= 0.1 mol/L KNO₃.The formation constants of binary and ternary complexes were obtained.The structures of the complexes and effects of substituents were also discussed.

Key words: Stability of complexes, Functionalized macrocyclic dioxotetraamine, a-Aminoacids, Copper(Ⅱ)

TrendMD:

XIAN Jing-Chun, ZHU Shou-Rong, LIN Hua-Kuan, CHEN Rong-Ti. Linear Free Energy Relationship of Complexes(ⅩⅤⅡ)──Studies on the Stability of Copper(Ⅱ)-Dioxotetraamine Macrocycles-α-Aminoacids Ternary Complexes[J]. Chem. J. Chinese Universities, 1994, 15(2): 163.

[1]	A Li, WANG Yong. Fluorescent Peptide Sensor for Detection of Copper Ions [J]. Chem. J. Chinese Universities, 2020, 41(12): 2736.
[2]	CHEN Pei-Pei, XU Jia, JIANG Yu-Ye, FENG Chen-Chen, GAO Cong-Jie. Preparation and Characterization of a Novel Anti-biofouling Ultrafiltration Membrane with Cu²⁺ Immobilization [J]. Chem. J. Chinese Universities, 2013, 34(3): 739.
[3]	CHAI Wei, LI Yue-Jie, XIE Zhuo-Feng, HUANG Yao-Dong, CHANG Ji-Young. Coordination and Crystal Structure of β-Ketoanilides [J]. Chem. J. Chinese Universities, 2012, 33(08): 1738.
[4]	LI Yong-Ling, ZHANG Jian-Gang, WEI Yan-Li, CHENG Fang-Qin. Detection of Cysteine in Aqueous Solution Based on Indicator Displacement by Ultraviolet-Visible and Colorimetric Methods [J]. Chem. J. Chinese Universities, 2012, 33(06): 1158.
[5]	YANG Shu-Ping, HAN Li-Jun, PAN Yan, WANG Da-Qi, ZHAO Cui, WANG Bo. Synthesis, Crystal Structure, Antibacterial Activity and Interaction with BSA of Copper(Ⅱ) Complex with Ligand N,N'-Bis(4-chlorobenzyl)propane-1,2-diamine [J]. Chem. J. Chinese Universities, 2012, 33(01): 14.
[6]	WANG Hong-Su, HUANG Jia-Hui, XU Chen, XU Ling, SONG Ke, XU Hai-Yan, WANG Zhu-Qian, KAN Qiu-Bin*. Synthesis, Characterization and Catalytic Performance of Copper(Ⅱ)-8-quinolinol Functionalized SBA-15 [J]. Chem. J. Chinese Universities, 2007, 28(7): 1333.
[7]	REN Hong¹, XU Jia-Ning², YU Lian-Xiang², YE Jun-Wei³, BI Ming-Hui¹, ZHANG Ping², SONG Tian-You¹. Hydrothermal Synthesis and Structure Characterization of a 2D Coordination Polymer [Cu(ox)(4,4'-bpy)]_n [J]. Chem. J. Chinese Universities, 2007, 28(6): 1014.
[8]	XU Gui-Yun^1,2, JIAO Kui², LI Yan-Tuan³, REN Yong², ZHANG Xu-Zhi². Electrochemical Studies on Interaction Between Dinuclear Copper(Ⅱ) Complex Containing Dimethylglyoxime and DNA [J]. Chem. J. Chinese Universities, 2007, 28(1): 49.
[9]	ZHANG Zun-Ting, WANG Qiu-Ya, HE Yun, WANG Xiao-Bing, XUE Dong, ZHENG Jian-Bin. Syntheses,Crystal Structures and Biological Activity of Bimethylation Daidzein Sulfonates [J]. Chem. J. Chinese Universities, 2005, 26(12): 2247.
[10]	ZHANG Zun-Ting, WANG Qiu-Ya, HE Yun, WANG Xiao-Bing, XUE Dong, ZHENG Jian-Bin. Syntheses,Crystal Structures and Biological Activity of Bimethylation Daidzein Sulfonates [J]. Chem. J. Chinese Universities, 2005, 26(12): 2247.
[11]	GUO Yan-He, GAO Dong-Zhao, LIN Hai, GE Qing-Chun, LIN Hua-Kuan, ZHU Shou-Rong . Stability, Kinetics of Acid Decomposition of Cu(Ⅱ) Complexes of Novel Polyamide-polyamino Ligand [J]. Chem. J. Chinese Universities, 2004, 25(1): 103.
[12]	GUO Wei, WANG Jing, HE Jia-Qi, XIA Zhi-Zhong, CHENG Jin-Pei. Synthesis of Nicotinoyl Disubstituted Pseudo-cyclopeptide and Its Coordination Behavior with Cu²⁺ [J]. Chem. J. Chinese Universities, 2003, 24(5): 837.
[13]	CHEN Shi, LU Tong-Bu, FENG Xiao-Long, LI Yan-Wu, MAO Zong-Wan, JI Liang-Nian . Synthesis, Structure and Stability of Binuclear Metal Complexes with Macrocyclic Ligand [J]. Chem. J. Chinese Universities, 2002, 23(6): 1004.
[14]	HE Shui-Yang, CAO Wen-Kai, CHEN Jun-Li, ZHAO Jian-She, SHI Qi-Zhen . Synthesis, Crystal Structure and Antibacterial Activity of Copper(Ⅱ) Complexes with 2-oxo-Propionic Acid Salicyloyl Hydrazone [J]. Chem. J. Chinese Universities, 2002, 23(6): 991.
[15]	GUO Xue-Yan, ZHU Wen-Xiang, YAN Xi, WANG Ru-Ji, LI Yong. Syntheses and Crystal Structures of Complexes Zinc and Copper(Ⅱ) Nitrates with 1,10-Dioxa-4,7,13,16-tetraazacyclooctadecane [J]. Chem. J. Chinese Universities, 2002, 23(10): 1842.

Linear Free Energy Relationship of Complexes(ⅩⅤⅡ)──Studies on the Stability of Copper(Ⅱ)-Dioxotetraamine Macrocycles-α-Aminoacids Ternary Complexes

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments