Syntheses of Derivatives of 3-(1'-carbonyl)-Ferrocenyl-2-crotonic Ester with Amphipaphy

Abstract

Abstract: The acylation reaction of 3-ferrocenyl-2-crotonic ester has been investigated.When It reacted with alkyl acyl chloride or benzyl chloride,the substitution reaction took place in the unsubstituted cyclopentadiene ring and just one single new product was obtained.But as it reacted with α,β-unsaturated acyl chloride,two new products were obtained in each reaction.Ten new compounds with amphiphilic structure were prepared.All of them were characterized by ¹H NMR,IRspectra and elemental analysis.

Key words: Ferrocenyl α,β-unsaturated ester, Synthesis, Acylation reaction

TrendMD:

ZHANG Cheng-Ru, YANG Kong-Zhang, YIN Rong-Jun. Syntheses of Derivatives of 3-(1'-carbonyl)-Ferrocenyl-2-crotonic Ester with Amphipaphy[J]. Chem. J. Chinese Universities, 1994, 15(1): 53.

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Syntheses of Derivatives of 3-(1'-carbonyl)-Ferrocenyl-2-crotonic Ester with Amphipaphy

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