Chemical Preparation and Mossbauer Investigation of Iron-Phosphorus-Boron Nanometer Metglass

Chem. J. Chinese Universities ›› 1993, Vol. 14 ›› Issue (5): 606.

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Chemical Preparation and Mossbauer Investigation of Iron-Phosphorus-Boron Nanometer Metglass

HU Zheng, FAN Yi-Ning, CHEN Yi

Department of Chemistry, Nanjing University, Nanjing, 210008

Received:1992-11-24 Revised:1993-03-25 Online:1993-05-24 Published:1993-05-24

Abstract

Abstract: By changing the initial pHvalue of the mixture solution of FeSO₄·7H₂Oand NaH₂PO₂·H₂O, Fe-P-Bnanometer metglass with different concentrations of Pand Bwas prepared by chemical reduction method.The content of Pdecreases and Bcontent increases with increasing pHof the mixture solution.Mossbauer experimental results indicate that Pand Bcan influence the magnetic moment of Fe atom to a certain extent, which could be well explained with electron-transfer model.

Key words: Nanometer, Metglass, Chemical reduction, Mossbauer spectrosoopy

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HU Zheng, FAN Yi-Ning, CHEN Yi. Chemical Preparation and Mossbauer Investigation of Iron-Phosphorus-Boron Nanometer Metglass[J]. Chem. J. Chinese Universities, 1993, 14(5): 606.

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Chemical Preparation and Mossbauer Investigation of Iron-Phosphorus-Boron Nanometer Metglass

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