A Study of the Reaction of C60 with Toluene, Benzyl Chloride and p-Xylene in Gas Phase

Chem. J. Chinese Universities ›› 1993, Vol. 14 ›› Issue (4): 563.

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A Study of the Reaction of C₆₀ with Toluene, Benzyl Chloride and p-Xylene in Gas Phase

GUO Xing-Hua¹, LIU Zi-Yang¹, SONG Feng-Rui¹, LIU Shu-Ying¹, ZHANG Fa-Yi²

1. Chmgckm Institute of Applied Chemistry, Acodemia Sixica, Changchun, 130022;
2. Department of Chemistry, Nmtai University, Tianjin

Received:1992-09-27 Revised:1992-12-02 Online:1993-04-24 Published:1993-04-24

Abstract

Abstract: In the ion source of mass spectrometer, the gas-phase C₆₀ reacted with the ion or radical fragments of toluene, benzyl chloride and p-xylene and a series of derivative ions were formed in the gas phase.This indicates the gas-phase C₆₀ has active chemical properties.Among them [C₆₀C₇H₇]⁺ and [C₆₀C₆H₅]⁺ are the predominant adduct ions.The C₇H₇⁺ ions are the mixture of tropylium, benzyl or tolyl ions in the gas phase, therefore the adduct ions [C₆₀C₇H₇]⁺ have four possible structures.

Key words: Buckminsterfullerene, Gas-phase ion-molecule reaction, Toluene, Benzyl chloride, p-Xylene

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GUO Xing-Hua, LIU Zi-Yang, SONG Feng-Rui, LIU Shu-Ying, ZHANG Fa-Yi. A Study of the Reaction of C₆₀ with Toluene, Benzyl Chloride and p-Xylene in Gas Phase[J]. Chem. J. Chinese Universities, 1993, 14(4): 563.

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A Study of the Reaction of C₆₀ with Toluene, Benzyl Chloride and p-Xylene in Gas Phase

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