Synthesis and Properties of Tetra(5,6-dichloro-1, 4-dithiacyclohexeno)-tetraazaporphyrin and Its Manganese (Ⅱ), Iron(Ⅱ), Nickel (Ⅱ), and Copper (Ⅱ) Complexes

Abstract

Abstract: Tetra(5,6-dichloro-1,4-dithiacyclohexeno)tetraazaporphyrin H₂TCTAPand its transition metal complexes MTCTAP( M = Mn(Ⅱ), Fe(Ⅱ), Ni(Ⅱ), Cu(Ⅱ)) have been synthesized by chlorization of chlorine-free tetraazaporphyrines, and characterized by elemental analysis, IR, and TG-DTA.H₂TCTAPand MTCTAPare thermostable at 427 and 450℃, respectivily.Its electron spectra in DMFhave been observed at -630 nm(Qband), 350 nm(Bband), and at -460 nm(flu-orescence).Electron paramagnetic resonace spectra of the CuTCTAPpowder at 77Khave given anisotropic tensors g_// = 2.308,g_⊥ = 2..067, A_// = - 0.133 cm^-1, A_⊥ = 0.079 cm^-1.

Key words: Thio-tetraazaporphyrin, Metal complex, Electron spectrum, Electron paramagnetic resonance spectrum

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TANG Yue-Qun, PENG Zheng-He, QIN Zi-Bin . Synthesis and Properties of Tetra(5,6-dichloro-1, 4-dithiacyclohexeno)-tetraazaporphyrin and Its Manganese (Ⅱ), Iron(Ⅱ), Nickel (Ⅱ), and Copper (Ⅱ) Complexes[J]. Chem. J. Chinese Universities, 1993, 14(1): 13.

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Synthesis and Properties of Tetra(5,6-dichloro-1, 4-dithiacyclohexeno)-tetraazaporphyrin and Its Manganese (Ⅱ), Iron(Ⅱ), Nickel (Ⅱ), and Copper (Ⅱ) Complexes

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