The Synthesis of 1,1' -Diselena Substituted Ferrocene Derivatives

Abstract

Abstract: In this paper, an improved method for the synthesis of 1,1'-diselena substituted ferrocene derivatives is given.It involves the reduction of 1, 2, 3-triselena[3]ferrocenophane by LiAlH₄ to form ferrocene 1,1'-diselenol, followed by the addition of an electrophile and triethy-lamine to the above reaction mixture to produce the title compounds in situ.Twelve such compounds were obtained, among which seven are new selenium-containing ferrocene derivatives.The structure of the products was identified by elemental analysis and ¹H NMRspectrum.Abrief discussion on the relationship between the ¹H and ⁷⁷Se NMR spectra and the structure is given.

Key words: Ferrocene derivative, Organoselenium compound, Organic synthesis

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LI Pu, SHI Shu-jian. The Synthesis of 1,1' -Diselena Substituted Ferrocene Derivatives[J]. Chem. J. Chinese Universities, 1992, 13(6): 770.

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The Synthesis of 1,1' -Diselena Substituted Ferrocene Derivatives

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