Studies on Electronic Structures and Spectra of Heteroatom-Substituted Porphyrins

Chem. J. Chinese Universities ›› 1992, Vol. 13 ›› Issue (11): 1452.

• Articles • Previous Articles Next Articles

Studies on Electronic Structures and Spectra of Heteroatom-Substituted Porphyrins

YANG Ming, WANG Zhi-Zhong, YANG Zhong-Zhi

Institute of Theoretical Chemistry, Jilin University, Changchun, 130023

Received:1992-01-29 Revised:1992-04-14 Online:1992-11-24 Published:1992-11-24

Abstract

Abstract: Systematical calculation studies on the electronic structures and singlet π→π^* transitions of free porphyrins and oxa-,thia-or aza-porphyrins have been made by using INDO/CImethod.Based on the frontier orbital characters and charge distributions the electronic structures of these compounds are discussed.The calculational results predict the spectra of lower energy transition of some heteroatom-substituted porphyrins.

Key words: Oxa-, thia- and aza-porphyrins, Electronic structures and spectra, INDO/CI method

TrendMD:

YANG Ming, WANG Zhi-Zhong, YANG Zhong-Zhi. Studies on Electronic Structures and Spectra of Heteroatom-Substituted Porphyrins[J]. Chem. J. Chinese Universities, 1992, 13(11): 1452.

[1]	LI Qiao, ZHAO Yang, WANG Enju. Moisture Absorption Reaction and Fluorescence Property of Highly Active Michael System Based on Arylidenemalononitrile [J]. Chem. J. Chinese Universities, 2022, 43(3): 20210690.
[2]	GAO Jing, HE Wentao, WANG Xinxin, XIANG Yushu, LONG Lijuan, QIN Shuhao. Preparation of DOPO Derivative Modified Carbon Nanotubes and Their Effect on Flame Retardancy of Polylactic Acid [J]. Chem. J. Chinese Universities, 2022, 43(3): 20210670.
[3]	Minwen JIANG,Chenhui YIN,Sheng LI,Xiaoli LI. Synthesis of DOPO-based Cyclotriphosphazene Macromolecule Flame Retardant and Its Performance in Flame-retarded Epoxy Resin ^† [J]. Chem. J. Chinese Universities, 2019, 40(12): 2615.
[4]	WU Yuxuan, DING Songdong, LIU Ning, HUANG Song, HUANG Huang, SU Dongping. New Method for Synthesis of Amide Podand Extractants^† [J]. Chem. J. Chinese Universities, 2014, 35(2): 257.
[5]	GUO Xue-Yan, ZHU Wen-Xiang, YAN Xi, WANG Ru-Ji, LI Yong. Syntheses and Crystal Structures of Complexes Zinc and Copper(Ⅱ) Nitrates with 1,10-Dioxa-4,7,13,16-tetraazacyclooctadecane [J]. Chem. J. Chinese Universities, 2002, 23(10): 1842.
[6]	TAI Xi Shi, TAN Min Yu, LIU Wei Sheng . Synthesis and Spectral Properties of the Complexes of Lanthanide Nitrates with 1,1,1-Tri-[1'-(2'-oxa-5'-oxo-6'-aza6'-bisphenyl)hexyl] Propane [J]. Chem. J. Chinese Universities, 2001, 22(2): 182.
[7]	XIE Yong-Shu, YU Jun, LIN Rui-Sen, LIU Qing-Liang . 4-Nitrophenyl Acetate Hydrolysis Catalyzed by Cu(Ê) and Zn(Ê) Complexes of Linear Oxa-Aza Polydentate Amino Alcoholic Phenol Ligands [J]. Chem. J. Chinese Universities, 2000, 21(9): 1441.
[8]	XIE Yong-Shu, KOU Fu-Ping, LIN Rui-Sen, ZONG Han-Xing . Synthesis of Linear Oxa-aza Ligands and Formation of Their Copper(Ⅱ) and Zinc(Ⅱ) Complexes [J]. Chem. J. Chinese Universities, 1998, 19(5): 676.
[9]	SHA Yao-Wu, CAI Meng-Shen. Chemistry of 1,2,4-Triazines (XXIV)──Synthesis of Pyrazolo-(5,4-e)-1,2,4-triazine Derivatives [J]. Chem. J. Chinese Universities, 1995, 16(4): 563.
[10]	WANG Xiao-Peng, LI Zhi-Ru, SUN Jia-Zhong. A Series of CI Calculations of Binuclear Iron Clusters [J]. Chem. J. Chinese Universities, 1994, 15(7): 1059.
[11]	TENG Qi-wen, FENG Ji-kang, XU Wen-guo, LI Zhi-ru . Quantum Chemical Study of Excited State Double Proton Transfer of the 7-Azaindole Dimer [J]. Chem. J. Chinese Universities, 1992, 13(4): 498.
[12]	Wang Zhi-zhong, Li Jun, Feng Ji-kang . Studies on Electronic Structures and Spectra of Ni Tetraphenylporphyrin [J]. Chem. J. Chinese Universities, 1991, 12(3): 365.
[13]	Ding Qizhu, Luo Xuangan, Zhuo Renxi . Studies on the Synthesis and Antitumor Activity of 3-(Arylmethyleneamino)propylsilatrane-Metal Complexes [J]. Chem. J. Chinese Universities, 1989, 10(12): 1254.
[14]	Ding Qizhu, Luo Xuangan, Zhuo Renxi . Studies on the Synthesis and Antitumor Activity of 3-Aminopropylsilatrane Derivatives [J]. Chem. J. Chinese Universities, 1989, 10(10): 1007.

Studies on Electronic Structures and Spectra of Heteroatom-Substituted Porphyrins

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 14

Recommended Articles

Metrics

Comments