The Synthesis of Zirconium Bis(Monooctyl Phosphate) and Indexing on its Polycrystalline X-ray Diffraction Pattern

Abstract

Abstract: A new Componnd of Zirconium bis(monooctyl phosphate) was prepared.The powder .crystals with higher crystallinity degree were obtained by HFacid recrystalization.The study of elemental analysis and IR, TGA, DTAshows that the molecular formula of zirconium bis (monooctyl phosphate) can be expressed as Zr(G₈H₁₇OPO₃)₂. The X-ray powder diffraction pattern of Zirconium bis(monooctyl phosphate) was determined and all X-ray diffraction lines were indexed.The indexing results show the crystal belongs to monoclinic system with simple mon-oclinic lattice.The cell parameters of the crystal here are a=1.699 nm, b=1.537 nm, c=2.454 nm, β=123.56°.Based on this each cell has 8 "molecules".

Key words: Zriconium bis(monooctyl phosphate), Preparation, Indexing of X-ray powder pattern, Determination of crystal structure

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WANG Bo, CHEN Yun-qing, WANG Zhen-jun . The Synthesis of Zirconium Bis(Monooctyl Phosphate) and Indexing on its Polycrystalline X-ray Diffraction Pattern[J]. Chem. J. Chinese Universities, 1992, 13(1): 103.

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The Synthesis of Zirconium Bis(Monooctyl Phosphate) and Indexing on its Polycrystalline X-ray Diffraction Pattern

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