Studies on the Complexes of Transition Metal with 2-[(2,4-Dichlorophenylamino)carbonyl]-benzoic Acids

Chem. J. Chinese Universities ›› 1991, Vol. 12 ›› Issue (9): 1157.

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Studies on the Complexes of Transition Metal with 2-[(2,4-Dichlorophenylamino)carbonyl]-benzoic Acids

Shi Jin-chao, Yang Bing-qin, Ma Huai-rang, Wang Zhang-fa

1. Departtnent of Chemistry, Nartliuxstern University, Xi'an, 710069;
2. Academy of Chemical Fertilizer, Sltaanxi

Received:1990-07-06 Online:1991-09-24 Published:1991-09-24

Abstract

Abstract: The complexes of transition metal with 2-[(2,4-dichlorophenylamino) carbonyl]-benzoic acids were prepared and characterized by elemental analysis,thermogravimetry, infrared and electronic spectra as well as nuclear magnetic resonance. The results show that the coordination occurs by means of two oxygen atoms, one is from the amido, and the other from the hydoxyl in the carboxylate. The complexes of Cu(I) are square planar, but the others are octahedral structures with only a small distortion. Some of the ligand field parameters were evaluated.

Key words: Transition metal complex, Coordination polyhedra, Infrared spectrometry, UV spec-trophotometry

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Shi Jin-chao, Yang Bing-qin, Ma Huai-rang, Wang Zhang-fa. Studies on the Complexes of Transition Metal with 2-[(2,4-Dichlorophenylamino)carbonyl]-benzoic Acids[J]. Chem. J. Chinese Universities, 1991, 12(9): 1157.

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Studies on the Complexes of Transition Metal with 2-[(2,4-Dichlorophenylamino)carbonyl]-benzoic Acids

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