XPS Study on Rare Earth Complexes with L-Glutamine

Chem. J. Chinese Universities ›› 1991, Vol. 12 ›› Issue (10): 1386.

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XPS Study on Rare Earth Complexes with L-Glutamine

Niu Chun-ji¹, Zhang Shu-gong¹, Wang Zeng-lin¹, Ni Jia-zuan¹, Nie Yu-xiu², Yin Xin², Xu Yi-lu²

1. Changchun Institute of Applied Chemistry, Academia Sinica, Changchun, 130022;
2. Institute of Basic Medical Science, Norman Bethune University of Medical Sciences, Changchun

Received:1990-06-30 Online:1991-10-24 Published:1991-10-24

Abstract

Abstract: The title complexes with a composition LnL₃Cl₃· 2H₂O(Ln=Eu,Tb,Ho and Tm; L=L-glutamine) were synthesized and characterized by XPS combined with elemental analysis, thermal analysis and IRspectra. The change of binding energies of O_1a, Ln_3d, Ln_4dand Cl_2p, took place obviously because of the coordination, and the satellite peaks appear in XPS3d spectrum of Eu complex. The mechanism of formation of satellite peak is discussed.

Key words: Rare earth complex, Glutamine, XPS, Satellite peak

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Niu Chun-ji, Zhang Shu-gong, Wang Zeng-lin, Ni Jia-zuan, Nie Yu-xiu, Yin Xin, Xu Yi-lu. XPS Study on Rare Earth Complexes with L-Glutamine[J]. Chem. J. Chinese Universities, 1991, 12(10): 1386.

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XPS Study on Rare Earth Complexes with L-Glutamine

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