Selective Hydroboration-Iodination of Terminal Alkenes Containing Ester Groups——Synthesis of Two Insect Sex Pheromones

Chem. J. Chinese Universities ›› 1990, Vol. 11 ›› Issue (8): 900.

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Selective Hydroboration-Iodination of Terminal Alkenes Containing Ester Groups——Synthesis of Two Insect Sex Pheromones

Pan Yijun, Xu Zhangbuang, den Jiawei, Jiang Jilong, Song Gongwu

Department of Chemistry, Hubei University, Wuhan

Received:1989-04-20 Online:1990-08-24 Published:1990-08-24

Abstract

Abstract: Terminal alkenes containing ester groups are converted to w-functional alkyl iodides through a hydroboration-iodihation reaction blinder a mild condition; All Of the three alkyl groups on borane can be used in this case. The insect sex pheromones of Törtrix Viridana and Adoxophes Orana Rod are synthesized in a higher (Z)-form purity by using the w-functiori terminal alkyl iodides.

Key words: Hydroboratioh-Iodination, Alkenes containing ester groups, Terminal alkyl iodides, Insect sex pheromone, Synthesis

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Pan Yijun, Xu Zhangbuang, den Jiawei, Jiang Jilong, Song Gongwu . Selective Hydroboration-Iodination of Terminal Alkenes Containing Ester Groups——Synthesis of Two Insect Sex Pheromones[J]. Chem. J. Chinese Universities, 1990, 11(8): 900.

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Selective Hydroboration-Iodination of Terminal Alkenes Containing Ester Groups——Synthesis of Two Insect Sex Pheromones

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