Studies on the Reaction of Photolysis of O-Acyl-a-Oximinoketones by the Method of Monte Carlo Simulation

Abstract

Abstract: Photoreactions were studied by means of Monte Carlo simulation for the first time. The experimental results of photolysis of five O-acyl-a-oximinoketones were compared with the results of Monte Carlo simulation and kinetic method. The conclusion shows that if the first order approximation of absorbed light, which makes the simultaneous differential equations solvable, is used in the kinetic method, the theoretical reaults deviate from the experimental results in the later period of the reaction. However, the Monte Carlo simulation could get rid of this approximation and agreed with the experiments very well.

Key words: O-acyl-a-oximinoketone, Monte Carlo simulation, Photolysis reactions

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Tong Wei-da, Yang Yu-liang, Sun Meng, Yu Tong-yin . Studies on the Reaction of Photolysis of O-Acyl-a-Oximinoketones by the Method of Monte Carlo Simulation[J]. Chem. J. Chinese Universities, 1990, 11(12): 1400.

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Studies on the Reaction of Photolysis of O-Acyl-a-Oximinoketones by the Method of Monte Carlo Simulation

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