Studies on Chemical Equilibrium of the Complex Reaction with the Method of Dimensionless Parameter

Abstract

Abstract: The method of dimensionless parameter of thermostatics for (2-1) type reversible reaction suggested in literatures was used to study the complex reaction of dibenzo-.18-crown-6 with sodium ion in DMSO-H₂O mixed solvents (800/200(V/V)) at 25. 0 and 30. 0℃ respectively.The enthalpy change and equilibrium constant of the reaction were directly measured. The applicable range of the method is discussed. The basic requirement for evaluating equilibrium constant K_a with extrapolation is also proposed in this paper.

Key words: Thermostatics, Method of dimensionless parameter, Complex reaction, Crown ether, Metal ion

TrendMD:

Zeng Xiancheng, Zhang Yuanqin, Deng Yu . Studies on Chemical Equilibrium of the Complex Reaction with the Method of Dimensionless Parameter[J]. Chem. J. Chinese Universities, 1990, 11(11): 1263.

References

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