Chem. J. Chinese Universities ›› 1990, Vol. 11 ›› Issue (1): 105.

• Articles • Previous Articles     Next Articles

Kinetics and Mechanism of Oxygen Atom Transfer Reactions to M3(CO)11L(M=Fe, Ru, Os)

Shen Jiankun, Gao Yici, Shi Qizhen   

  1. Department of Chemistry, Lanzhou University, Lanzhou
  • Received:1988-04-25 Online:1990-01-24 Published:1990-01-24

Abstract: Detailed kinetic data are reported for substitution reactions of M3(CO)11L(M=Fe, Ru, Os) in CHCl3 in the presence of Me3NO. Amechanism is proposed, and the effects of substituted ligands are discussed.

Key words: Metal carbonyls, Trimethylamine N-oxide, O-Atom transfer reactions, Kinetics and mech- anism

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