Chem. J. Chinese Universities ›› 1989, Vol. 10 ›› Issue (8): 817.
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Liu Yiyin, Wang Jiabing, Liang Ge, Wang Jitao
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Abstract: The Titano-hydrogenation of Alkyne hydrocarbons was studied by the method of G.C.track.At the early stage the cis-alkene hydrocarbons were obtained with a higher selectivity and a good yield, but trans-ethenes were obtained with a higher selectivity and a good yield at the later stage of the reaction.Controlling the time of the reaction and quenching with ketones,a series of new stere-ospecific allyl alcohols were obtained.
Key words: Alkyne hydrocarbons, Titano-hydrogenation, Stereo-selectivity, Allyl alcohols
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Liu Yiyin, Wang Jiabing, Liang Ge, Wang Jitao . Titano-hydrogenation of Alkyne Hydrocarbons and Stereoscopic Structure of Products[J]. Chem. J. Chinese Universities, 1989, 10(8): 817.
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http://www.cjcu.jlu.edu.cn/EN/Y1989/V10/I8/817