Chem. J. Chinese Universities ›› 1989, Vol. 10 ›› Issue (8): 817.

• Articles • Previous Articles     Next Articles

Titano-hydrogenation of Alkyne Hydrocarbons and Stereoscopic Structure of Products

Liu Yiyin, Wang Jiabing, Liang Ge, Wang Jitao   

  1. Institute of Elemento-Organic Chemistry, Naikai Univerity, Tianjin
  • Received:1988-01-31 Online:1989-08-24 Published:1989-08-24

Abstract: The Titano-hydrogenation of Alkyne hydrocarbons was studied by the method of G.C.track.At the early stage the cis-alkene hydrocarbons were obtained with a higher selectivity and a good yield, but trans-ethenes were obtained with a higher selectivity and a good yield at the later stage of the reaction.Controlling the time of the reaction and quenching with ketones,a series of new stere-ospecific allyl alcohols were obtained.

Key words: Alkyne hydrocarbons, Titano-hydrogenation, Stereo-selectivity, Allyl alcohols

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