Chem. J. Chinese Universities ›› 1989, Vol. 10 ›› Issue (10): 1022.
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Li Changming, Zha Quanxing, Yang Lin, Li Xiang
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Abstract: The electrochemical catalysis behavior of thionyl chloride reduction with metal- tetram-ethoxyphenyl porphyrins is studied.The experimental results demonstrate that metal porphyrins possess a higher activity for thionyl chloride reduction and the order of the activity of porphyrins with different central ions is Fe≈Co>Ni.In the other hand, these complexes seem to retard the deposition of LiCl on the electrode surface and to inhance the discharge capacity of Li/SOCl2 batteries.
Key words: Metal-porphyrins complex, Thionyl chloride reduction
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Li Changming, Zha Quanxing, Yang Lin, Li Xiang . The Electrochemical Catalysis Behavior of Metal-Porphyrins for Thionyl Chloride Reduction[J]. Chem. J. Chinese Universities, 1989, 10(10): 1022.
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