Synthesis of the Precursor of Acyloin Derivatives of Ferrocene——2-Ferrocenyl-2-(Aryl Hydroxymethyl)-1,3-Dithiane

Chem. J. Chinese Universities ›› 1989, Vol. 10 ›› Issue (10): 1017.

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Synthesis of the Precursor of Acyloin Derivatives of Ferrocene——2-Ferrocenyl-2-(Aryl Hydroxymethyl)-1,3-Dithiane

Sun Lijun, Shi Shujian

Beijing Institute of Chemical Technology, Beijing

Received:1988-05-10 Online:1989-10-24 Published:1989-10-24

Abstract

Abstract: The aim of this work is to develop a new route for the synthesis of ferrocenyl acyloin derivatives.The route consists of the reaction of 2-ferrocenyl- 1, 3-dithiane with aryl carbonyl compounds to form a class of intermediates, 2-ferrocenyl- 2- (aryl hydroxylmethyl)-l,3-dithianes(Ⅲ), which are then hydrolyzed to afford the desired products.In this paper we only report the synthesis and some properties of the intermediates (Ⅲ).Sixteen of the intermediates (Ⅲ) are obtained, they are all new ferrocene derivatives.

Key words: Acyloin, Dithiane, Ferrocene derivative

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Sun Lijun, Shi Shujian . Synthesis of the Precursor of Acyloin Derivatives of Ferrocene——2-Ferrocenyl-2-(Aryl Hydroxymethyl)-1,3-Dithiane[J]. Chem. J. Chinese Universities, 1989, 10(10): 1017.

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Synthesis of the Precursor of Acyloin Derivatives of Ferrocene——2-Ferrocenyl-2-(Aryl Hydroxymethyl)-1,3-Dithiane

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