Synthesis and Magnetism of Copper(Ⅱ)-Cobalt(Ⅱ)Complexes with N,N'-Ethylenedisalicylamidatocuprate(Ⅱ)

Abstract

Abstract: New binuclear complexes of type [Cu(samen)Co(L)]₂ were synthesized,where samen 4- denotes N,N'-ethylenedisalicylamidate anion and Ldenotes 2,2'-dipyridyl or 1,10-phenanthrolirie. Based on IR, elemental analyses and electronic spectra, the complexes are proposed to consist of a Cu(Ⅱ) in a distorted planar environment and Cod) in a distorted octahedron. The magnetisms of the Cu(Ⅱ)-Co(Ⅱ) complexes were well interpreted in terms of the susceptibility equation based on Heisenberg model.

Key words: Binuclear complex, Copper (Ⅱ)-cobalt (Ⅱ), Magnetism

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Liao Daizheng . Synthesis and Magnetism of Copper(Ⅱ)-Cobalt(Ⅱ)Complexes with N,N'-Ethylenedisalicylamidatocuprate(Ⅱ)[J]. Chem. J. Chinese Universities, 1988, 9(7): 647.

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Synthesis and Magnetism of Copper(Ⅱ)-Cobalt(Ⅱ)Complexes with N,N'-Ethylenedisalicylamidatocuprate(Ⅱ)

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