Chem. J. Chinese Universities ›› 1986, Vol. 7 ›› Issue (7): 605.

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The Study on Halogen Substituted Benzoylferrocenes and Their Reduction Products—Corresponding Alcohols

Zhang Yuhung1, Zhang Jiankuo1, Shi Shujian1, Chen Shoushan2   

  1. 1. Department of Chemistry, Inner Mongolia Unitersity, Huhehot;
    2. Institute of ElementO-argarie Chemistry, Nankai University, Tiaijin
  • Received:1985-03-26 Online:1986-07-24 Published:1986-07-24

Abstract: All of the o,m,p-halogen substituted benzoylferrocenes have been prepared from ferrocene and halogen substituted benzoylchloride by Frieded-Crafts acylation.The ketenes were reduced to the corresponding halogen substituted phenylferrocenyl-methanols with LiAlH4 or KBH4 Sixteen of them are new compounde.The sythesis results and characteristics of IRand 1H NMRspectra of all the above mentioned compounds were preliminarily discussion.

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