Chem. J. Chinese Universities ›› 1986, Vol. 7 ›› Issue (12): 1109.

• Articles • Previous Articles     Next Articles

The Synthesis,Reaction and Catalytic Activity of Morpho-line Coordinated Molybdenum and Tungsten Carbonyls

Zhang Zhengzhi1, Wang Xukun1, Zhao Weijun2, Zhang Shuji2, Fang Yanquaa2, Liu Maoping2   

  1. 1. Institute of Elementoorganio Chemistry, Nankai University, Tianjin;
    2. Department of Chemistry, Nankai University, Tianjin
  • Received:1985-09-26 Online:1986-12-24 Published:1986-12-24

Abstract: Aprocedure for large amount of preparation of cis-bis(Lewis base)coordinated molybdenum and tungsten carbonyls is proposed.The structures of these new compounds are discussed and their exchange reaction with tertiary phosphines as well as their catalytic activity for carbonylation of methanol was studied.

TrendMD: