Chem. J. Chinese Universities ›› 1986, Vol. 7 ›› Issue (12): 1098.

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Studies on Michael-Type Reaction of (μ-Mercapto)-μ-Alkylthio) Bis (Tricarbonyliron)(Ⅲ)-Synthesis of (μ-3-Oxobutylthio)(μ-Alkylthio) Bis (Tricarbonyliron) and Reactivity of α,β-Unsaturated Substrates

Song Licheng, Zhao Zhengyun, Hu Qingmei, Wang Jitao   

  1. Department of Chemistry, Nankai University, Tianjin
  • Received:1985-09-12 Online:1986-12-24 Published:1986-12-24

Abstract: Amichael-type rea ction of a series of(μ-mercapto)(μ-alkylthio)bis(tricarbony-liron)s,(μ-HS)(μ-RS)Fe2(CO)6(A),with methyl vinyl ketone can take place to give unsymmetrically novel Fe-Scluster complexes containing 3-oxobutyl group,(这里有图片19861210-1098-1.gif).This Michael reaction is characterizedby.

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