Chem. J. Chinese Universities ›› 1984, Vol. 5 ›› Issue (3): 339.

• Preface • Previous Articles     Next Articles

SYNTHESIS AND REACTION OF BIS(CYCLOPENTENYLCYCLOPENTADIENYL) Ⅳ B GROUP METAL DERIVATIVES

Chen Shoushan, Wei Rongbao, Wang Jitao   

  1. Institute of Elemenlo-Organic Chemistry, Nankai University, Tianjin
  • Received:1982-11-02 Online:1984-06-24 Published:1984-06-24

Abstract: Bis (cyclopentenylcyclopentadienyl) metal dihalides, (RC5H4)3MX3 (M=Ti,Zr,Hf,R= <这里有图片19840310-339-1.gif> X=F,Cl,Br) and diaryl, disulfocyanide, dihydrosulfide derivatives have been synthesized. The double bond of cyclopentenyl on Cp with HBr, halogen underwent normal electrophilic addition reaction. The 1H NMRspectra of aformentioned derivatives are discussed.

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