Synthesis and Electrochromic Performance of Phosphazene-viologen Polymer †

doi:10.7503/cjcu20190541

Abstract

Abstract:

Electrochromic materials have attracted considerable attention due to their versatile applications in academic and industrial areas. In this work, a novel organic-inorganic hybrid electrochromic material(denoted as PHV ²⁺) was synthesized, which contains six viologen moieties and a hexachlorocyclotriphosphazene core. The structure of the polymer was characterized by Fourier transform infrared spectroscopy(FTIR), X-ray diffraction(XRD) and nuclear magnetic resonance. The water solubility makes it possible to construct an electrochromic hydrogel with polyvinyl alcohol by a simple method, which has the advantages of low cost and no toxicity. The electrochromic device made of this polymer exhibits good electrochromic properties with good cyclic stability. The device undergoes a noticeably yellowish-purple color change at a voltage of 2.1 V. The optical contrast of the device is 62.19% at 526 nm. This electrochromic polymer shows its potential in electrochromic application.

Key words: Viologen, Phosphazene, Electrochromism, Polyvinyl alcohol gel electrolyte

CLC Number:

O621.3
O631

TrendMD:

SUN Mengying,Lü Jingchun,XU Hong,ZHANG Linping,ZHONG Yi,CHEN Zhize,SUI Xiaofeng,MAO Zhiping. Synthesis and Electrochromic Performance of Phosphazene-viologen Polymer ^†[J]. Chem. J. Chinese Universities, 2020, 41(6): 1399.

Figures/Tables 13

Sample	$T a 5 %$ /℃	$T b max$ /℃	Residue at T_max(%)	Mass loss rate at T_max(%·min^-1)	Residue at 600 ℃(%)
HCTP-CH₂Cl	290	346	88.45	3.83	66.36
EBV⁺	180	277	30.83	23.61	2.12
PHV²⁺	220	265	64.37	6.32	29.48

Sample	$T a 5 %$ /℃	$T b max$ /℃	Residue at T_max(%)	Mass loss rate at T_max(%·min^-1)	Residue at 600 ℃(%)
HCTP-CH₂Cl	290	346	88.45	3.83	66.36
EBV⁺	180	277	30.83	23.61	2.12
PHV²⁺	220	265	64.37	6.32	29.48

References 19

[1]	Madasamy K., Velayutham D., Suryanarayanan V., Kathiresan M., Ho K. C., J. Mater. Chem. C, 2019, 7(16), 4622—4637 doi: 10.1039/C9TC00416E URL
[2]	Wang J., Lu Y., Li H., Liu J., Yu S., J. Am. Chem. Soc., 2017, 139(29), 9921—9926
[3]	Mishra S., Yogi P., Saxena S. K., Roy S., Sagdeo P. R., Kumar R., J. Mater. Chem. C, 2017, 5(36), 9504—9512 doi: 10.1039/C7TC02913F URL
[4]	Ledwon P., Andrade J. R., Lapkowski M., Pawlicka A., Electrochimica Acta, 2015, 159, 227—233 doi: 10.1016/j.electacta.2015.01.168 URL
[5]	Li H. Y., Wei Y. L., Dong X. Y., Zong S. Q., Mak T. C. W., Chem. Mater., 2015, 27(4), 1327—1331
[6]	Toma O., Mercier N., Allain M., Kassiba A. A., Bellat J. P., Weber G., Bezverkhyy I., Inorg. Chem., 2015, 54(18), 8923—8930 doi: 10.1021/acs.inorgchem.5b00975 URL
[7]	Kim J. W., Myoung J. M., Adv. Funct. Mater., 2019, 29(13), 1808911 doi: 10.1002/adfm.v29.13 URL
[8]	Hu M. L., Xing F. F., Zhao Y. M., Bai Y. L., Li M. X., Zhu S. R., ACS Omega, 2017, 2(3), 1128—1133
[9]	Sui Q., Yuan Y., Yang N. N., Li. X., Gong T., Gao E. Q., Wang L., J. Mater. Chem. C, 2017, 5(47), 12400—12408 doi: 10.1039/C7TC04208F URL
[10]	Sydam R., Deepa M., J. Mater. Chem. C, 2013, 1(47), 7930—7940
[11]	Alesanco Y., Palenzuela J., Viñuales A., Cabañero G., Grande H. J., Odriozola I., ChemElectroChem, 2015, 2(2), 218—223
[12]	Dubal D. P., Chodankar N. R., Kim D. H., Gomez-Romero P., Chem. Soc. Rev., 2018, 47(6), 2065—2129
[13]	Huang D. C., Wu J. T., Fan Y. Z., Liou G. S., J. Mater. Chem. C, 2017, 5(36), 9370—9375
[14]	Das G., Prakasam T., Nuryyeva S., Han D. S., Abdel-Wahab A., Olsen J.C., Polychronopoulou K., Platas-Iglesias C., Ravaux F., J. Mater. Chem. A, 2016, 4(40), 15361—15369
[15]	Wadhwa K., Nuryyeva S., Fahrenbach Albert C., Elhabiri M., Platas-Iglesias C., Trabolsi A., J. Mater. Chem. C, 2013, 1(12), 2302—2307
[16]	Wang C., Wu L. P., Dai Y. M., Zhu Y. X., Wang B. J., Zhong Y., Zhang L. P., Sui X. F., Xu H., Mao Z. P., Polym. Degrad. Stab., 2018, 154, 239—247
[17]	Rao S. Q., Synthesis and Characteristics of Hydrogels Formed by Chitosan/poly(vinyl alcohol), Hubei University, Wuhan, 2014
	( 饶思奇 . 壳聚糖/聚乙烯醇水凝胶的制备及其性能研究, 武汉: 湖北大学, 2014)
[18]	Zhao S., Huang W., Guan Z., Jin B., Xiao D., Electrochimica Acta, 2019, 298, 533—540
[19]	Zhang X. P., Chen G. P. , Journal of Southeast University 1996, 26(3), 110—114
	( 张旭苹, 陈国平 . 东南大学学报, 1996, 26(3) 110—114)