High Efficiently co-Catalytic Oxidation Bio-guaiacol to Vanillin by Co2+/Ni2+

doi:10.7503/cjcu20180187

Abstract

Abstract: A catalytic oxidation system involving transition metals Co²⁺ and Ni²⁺ was studied for high-efficiency vanillin preparation under alkaline conditions. The catalytic system could efficiently convert a variety of biomass guaiacol into vanillin rapidly in low O₂ pressure. Using the density functional theory(DFT), the molecular model of the reactants was constructed and the reaction activity of the substituent group was verified by analyzing the electron cloud density of α-carbon and β-carbon. Furthermore, considering the reaction taken place in a closed environment with the presence of CH₃OH and O₂ under high temperature and pressure, the safety experiments were employed to ensure the experiment carrying out under safety condition. It also had important guiding significance to industrial production in the future.

Key words: Guaiacol, Vanillin, CH₃OH-O₂ system, Safety examination

CLC Number:

O625

TrendMD:

MAO Haifang, ZHANG Bo, HU Xiaojun, CAI Jiaoyang, MEI Tiantian, LIU Jibo, ZHANG Xiaoliang. High Efficiently co-Catalytic Oxidation Bio-guaiacol to Vanillin by Co²⁺/Ni²⁺[J]. Chem. J. Chinese Universities, 2018, 39(8): 1691.

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High Efficiently co-Catalytic Oxidation Bio-guaiacol to Vanillin by Co²⁺/Ni²⁺

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