Chem. J. Chinese Universities ›› 2016, Vol. 37 ›› Issue (12): 2191.doi: 10.7503/cjcu20160487
• Physical Chemistry • Previous Articles Next Articles
WANG Zhicheng1, XI Hailing1,2,*(), KONG Lingce1, ZHAO Sanping2, ZUO Yanjun1
Received:
2016-07-08
Online:
2016-12-10
Published:
2016-11-18
Contact:
XI Hailing
E-mail:fhxihl@163.com
CLC Number:
TrendMD:
WANG Zhicheng, XI Hailing, KONG Lingce, ZHAO Sanping, ZUO Yanjun. Kinetics and Mechanism of Decontamination Reaction of CEES in H2O2/[CnMIm]HCO3†[J]. Chem. J. Chinese Universities, 2016, 37(12): 2191.
IL | 1H NMR (600 MHz, CDCl3), δ | 13C NMR (600 MHz, CDCl3), δ | |
---|---|---|---|
[EMIm]HCO3 | 1.61(t, 3H), 3.74(s, 3H), 4.43—4.44(m, 2H), 7.73—7.74(d, 2H), 10.13(s, 1H) | 16.18, 37.12, 45.65, 122.61, 124.26, 137.08 | |
[BMIm]HCO3 | 0.86(t, 3H), 1.38(m, 2H), 1.89—1.91(m, 2H), 3.91(s, 3H), 4.22(t, 2H), 7.59(s, 1H), 7.70(s, 1H), 10.05(s, 1H) | 13.99, 19.95, 32.66, 37.28, 50.30, 122.78, 124.38, 137.48 | |
[HMIm]HCO3 | 0.87(t, 3H), 1.30—1.31(m, 6H), 1.91(m, 2H), 3.84(s, 3H), 4.32 (t, 2H), 7.54 (s, 1H), 7.69 (s, 1H), 9.88 (s, 1H) | 14.42, 22.84, 26.33, 30.69, 31.55, 37.22, 50.54, 122.69, 124.41, 137.29 | |
[OMIm]HCO3 | 0.87(t, 3H), 1.25—1.33(m, 8H), 1.90—1.91(m, 2H), 3.85(s, 3H), 4.32(t, 2H), 7.50(s, 1H), 7.67(s, 1H), 10.03(s, 1H) | 14.61, 23.11, 28.79, 29.50, 29.58, 30.85, 32.21, 37.35, 50.67, 122.62, 124.42, 137.58 |
Table 1 1H NMR and 13C NMR data of compounds [CnMIm]HCO3(n=2, 4, 6, 8)
IL | 1H NMR (600 MHz, CDCl3), δ | 13C NMR (600 MHz, CDCl3), δ | |
---|---|---|---|
[EMIm]HCO3 | 1.61(t, 3H), 3.74(s, 3H), 4.43—4.44(m, 2H), 7.73—7.74(d, 2H), 10.13(s, 1H) | 16.18, 37.12, 45.65, 122.61, 124.26, 137.08 | |
[BMIm]HCO3 | 0.86(t, 3H), 1.38(m, 2H), 1.89—1.91(m, 2H), 3.91(s, 3H), 4.22(t, 2H), 7.59(s, 1H), 7.70(s, 1H), 10.05(s, 1H) | 13.99, 19.95, 32.66, 37.28, 50.30, 122.78, 124.38, 137.48 | |
[HMIm]HCO3 | 0.87(t, 3H), 1.30—1.31(m, 6H), 1.91(m, 2H), 3.84(s, 3H), 4.32 (t, 2H), 7.54 (s, 1H), 7.69 (s, 1H), 9.88 (s, 1H) | 14.42, 22.84, 26.33, 30.69, 31.55, 37.22, 50.54, 122.69, 124.41, 137.29 | |
[OMIm]HCO3 | 0.87(t, 3H), 1.25—1.33(m, 8H), 1.90—1.91(m, 2H), 3.85(s, 3H), 4.32(t, 2H), 7.50(s, 1H), 7.67(s, 1H), 10.03(s, 1H) | 14.61, 23.11, 28.79, 29.50, 29.58, 30.85, 32.21, 37.35, 50.67, 122.62, 124.42, 137.58 |
Fig.1 Decontamination efficacy of CEES by H2O2 in different solventsa. [EMIm]HCO3; b. [BMIm]HCO3; c. [HMIm]HCO3; d. [OMIm]HCO3; e. [BMIm]DCA; f. [BMIm]NTf2; g. C2H5OH; h. H2O. Experimental conditions: m(CEES)=10 mg, solvents 420 μL, 30% H2O2 aqueous solution 80 μL, n(oxidant)∶n(CEES)=10, 30 min.
Fig.2 Decontamination efficacy of CEES using H2O2/[BMIm]HCO3 at different temperaturesExperimental conditions: c(CEES)=20 mg/mL,n(oxidant)∶n(CEES)=10, 30 min. Temperature/K:a. 243; b. 253; c. 273; d. 298; e. 313.
Fig.6 CL kinetics of H2O2 in lucigenin solution which containing basic ILsa. [BMIm]HCO3; b. [BMIm]DCA; c. [BMIm]NTf2.Experimental conditions: 2 mL lucigenin, 100 μL H2O2, 50 μL ILs.
Fig.7 Formation dynamics of ·O2- in H2O2/[BMIm]HCO3Curves a—g were the FTIR spectrum of H2O2/[BMIm]HCO3 mixture at 1, 2, 5, 10, 15, 20, 30 min, respectively.Inset: the growth trend of ·O2- was fitted bo a logarithmic function.
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