Synthesis and Photoluminescence Properties of β-Ga2O3∶Cr3+ Persistent Luminescence Nanoparticles with Near-infrared Afterglow†

doi:10.7503/cjcu20160006

Abstract

Abstract:

Cr³⁺ doped gallium oxide(β-Ga₂O₃∶Cr³⁺) nanoparticles with near infrared(NIR) persistent luminescence properties were prepared by a facile precipitation method with triethylene glycol as a surface ligand. The persistent luminescence properties and crystal structure of the Ga₂O₃∶Cr³⁺ nanoparticles highly depended on pH value of the reaction solution and the sintering temperature. The experimental results showed that pure β-Ga₂O₃∶Cr³⁺ nanocrystal with small grain size(ca. 30 nm) was obtained after pH value of the reaction solution was adjusted to 7 with ammonium hydroxide, and calcined in air at 700 ℃ for 3 h. The maximum afterglow emission wavelength of the β-Ga₂O₃∶Cr³⁺ nanoparticles was 750 nm, which was controlled by the reaction conditions. The NIR afterglow time of the β-Ga₂O₃∶Cr³⁺ nanoparticles was estimated to be longer than 384 h. The β-Ga₂O₃∶Cr³⁺ persistent luminescence nanoparticles with small size, long NIR afterglow time and controllable emission band have great potential application in low background noise and deep tissue in-vivo imaging.

Key words: Gallium oxide, Nanoparticles, Persistent luminescence, Near-infrared afterglow, Optical imaging

CLC Number:

O614

TrendMD:

ABDUKAYUM Abdukader, ABDURAHMAN Renagul, TUERDI Ailijiang, MAMATIMIN Adil. Synthesis and Photoluminescence Properties of β-Ga₂O₃∶Cr³⁺Persistent Luminescence Nanoparticles with Near-infrared Afterglow^†[J]. Chem. J. Chinese Universities, 2016, 37(5): 810.

Figures/Tables 10

Fig.1 Emission spectra of the Ga2O3∶Cr3+ nanoparticles prepared at different annealing temperatures(A) and different pH values(B)(A) a. Without annealing; b. 500 ℃; c. 700 ℃. (B) pH: a. 7; b. 9; c. 11; d. 13.

Fig.2 XRD patterns of the Ga2O3∶Cr3+ nanoparticles prepared at different annealing temperatures(A) and different pH values(B)(A) a. Without annealing; b. 500 ℃; c. 700 ℃. (B) pH: a. 7; b. 9; c. 11; d. 13.

Fig.3 TEM images(A) and size distribution histogram(B) of the as-prepared Ga2O3∶Cr3+ nanoparticles

Fig.4 Excitation spectrum of the Ga2O3∶Cr3+ nanoparticles

Fig.5 Persistent luminescence spectra of the Ga2O3∶Cr3+ nanoparticles at 10(a), 15(b), 20(c), 30(d), 40(e), 50(f), 60(g) min after stopping excitation

Fig.6 NIR afterglow decay curve of the Ga2O3∶Cr3+

Table 1 The parameters of NIR afterglow decay curve fitting

τ₁/s	A₁	τ₂/s	A₂	τ₃/s	A₃
240.4±2.94	816.49 ±6.75	21.27±0.06	3407.33±4.73	1005.21±25.72	296.66±7.72

Fig.7 NIR afterglow images of the Ga2O3∶Cr3+ nanoparticles at different time

Fig.8 Thermoluminescence glow curve of Ga2O3∶Cr3+ nanoparticles(A) and the NIR afterglow decay curve of the Ga2O3∶Cr3+ nanoparticles at different temperatures(B)(B) Temperature/℃: a. 30; b. 50; c. 70; d. 90.

Fig.9 NIR persistent luminescence mechanism in the Ga2O3∶Cr3+ nanoparticles

References 36

[1]	Smet P. F., Poelman D., Hehlen M. P., Opt. Mater.Express, 2012, 2(4), 452—454
[2]	Lastusaari M., Laamanen T., Malkamäki M., Eskola K. O., Kotlov A., Carlson S., Welter E., Brito H. F., Bettinelli M., Jungner H., Hölsä J., Eur. J.Mineral., 2012, 24(5), 885—890
[3]	Zuo Y. Y., Chen X., Liu X. B., Chem. Res. ChineseUniversities, 2015, 31(3), 427—429
[4]	Matsuzawa T., Aoki Y., Takeuchi N., Murayama Y., J. Electrochem. Soc., 1996, 143(8), 2670—2673
[5]	van den Eeckhout K., Smet P. F., Poelman D., Materials, 2010, 3(4), 2536—2566
[6]	van den Eeckhout K., Poelman D., Smet P., Materials, 2013, 6(7), 2789—2818
[7]	Pan Z., Lu Y. Y., Liu F., Nat.Mater., 2012, 11(1), 58—63
[8]	Bünzli J. C. G., Eliseeva S. V., Chem.Sci., 2013, 4(5), 1939—1949
[9]	Singh S. K., RSC Adv., 2014, 4(102), 58674—58698
[10]	Maldiney T., Viana B., Bessière A., Gourier D., Bessodes M., Scherman D., Richard C., Opt.Mater., 2013, 35(10), 1852—1858
[11]	Huang P., Tu D., Zheng W., Zhou S., Chen Z., Chen X., Science ChinaMaterials, 2015, 58(2), 156—177
[12]	Weissleder R., Nat.Biotechnol., 2001, 19(4), 316—317
[13]	Wang J. M., Zhu C. N., Zhu D. L., Tian Z. Q., Lin Y., Pang D. W., Chem. J. Chinese Universities,2015, 36(7), 1264—1268
	(王佳梅, 朱春楠, 朱东亮, 田智全, 林毅, 庞代文. 高等学校化学学报, 2015, 36(7), 1264—1268)
[14]	le masne de Chermont Q., Chaneac C., Seguin J., Pelle F., Maitrejean S., Jolivet J. P., Gourier D., Bessodes M., Scherman D., Proc. Natl. Acad. Sci. USA, 2007, 104(22), 9266—9271
[15]	Abdukayum A., Chen J. T., Zhao Q., Yan X. P., J. Am. Chem.Soc., 2013, 135(38), 14125—14133
[16]	Abdukayum A., Yang C. X., Zhao Q., Chen J. T., Dong L. X., Yan X. P., Anal.Chem., 2014, 86(9), 4096—4101
[17]	Maldiney T., Bessière A., Seguin J., Teston E., Sharma S. K., Viana B., Bos A. J., Dorenbos P., Bessodes M., Gourier D., Nat.Mater., 2014, 13(4), 418—426
[18]	Shi J., Sun X., Li J., Man H., Shen J., Yu Y., Zhang H., Biomaterials, 2014, 37C, 260—270
[19]	Chen D., Chen Y., Lu H., Ji Z., Inorg.Chem., 2014, 53(16), 8638—8645
[20]	Xu J., Chen D., Yu Y., Zhu W., Zhou J., Wang Y., Chem. AsianJ., 2014, 9(4), 1020—1025
[21]	Bessière A., Sharma S. K., Basavaraju N., Priolkar K. R., Binet L., Viana B., Bos A. J. J., Maldiney T., Richard C., Scherman D., Gourier D., Chem.Mater., 2013, 26(3), 1365—1373
[22]	Basavaraju N., Sharma S., Bessière A., Viana B., Gourier D., Priolkar K. R., J. Phys. D Appl. Phys., 2013, 46(37), 375401
[23]	Yan W., Liu F., Lu Y. Y., Wang X. J., Yin M., Pan Z., Opt.Express, 2010, 18(19), 20215—20221
[24]	Macfarlane P. I., Han T. P. J., Henderson B., Kaminskii A. A., Opt.Mater., 1994, 3(1), 15—24
[25]	Bessiere A., Jacquart S., Priolkar K., Lecointre A., Viana B., Gourier D., Opt.Express, 2011, 19(11), 10131—10137
[26]	Lu Y. Y., Liu F., Gu Z., Pan Z., J.Lumin., 2011, 131(12), 2784—2787
[27]	Farvid S. S., Wang T., Radovanovic P. V., J. Am. Chem.Soc., 2011, 133(17), 6711—6719
[28]	Wang X. S., Li W. S., Situ J. Q., Ying X. Y., Chen H., Jin Y., Du Y. Z., RSC Adv., 2015, 5(17), 12886—12889
[29]	Teston E., Richard S., Maldiney T., Lievre N., Wang G. Y., Motte L., Richard C., Lalatonne Y., Chem. Eur.J., 2015, 21(20), 7350—7354
[30]	Srivastava B. B., Kuang A., Mao Y., Chem.Commun., 2015, 51(34), 7372—7375
[31]	Li Z., Zhang Y., Wu X., Huang L., Li D., Fan W., Han G., J. Am. Chem.Soc., 2015, 137(16), 5304—5307
[32]	Kim J. S., Kim J. S., Park H. L., Solid StateCommun., 2004, 131(12), 735—738
[33]	Liu Z., Jing X., Wang L., J. Electrochem. Soc., 2007, 154(6), H500—H506
[34]	Rodrigues L. C. V., Brito H. F., Hölsä J., Stefani R., Felinto M. C. F. C., Lastusaari M., Laamanen T., Nunes L. A. O., J. Phys. Chem.C, 2012, 116(20), 11232—11240
[35]	Liu F., Yan W., Chuang Y. J., Zhen Z., Xie J., Pan Z., Sci.Rep., 2013, 3, 1554—1563
[36]	Li Y., Gecericius M., Qiu J., Chem. Soc.Rev., 2016, 45(8), 2090—2136

Synthesis and Photoluminescence Properties of β-Ga₂O₃∶Cr³⁺Persistent Luminescence Nanoparticles with Near-infrared Afterglow^†

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