Performance of Gas Storage in Carex meyeriana Kunth-based Carbon†

doi:10.7503/cjcu20160076

Abstract

Abstract:

Carex meyeriana Kunth was chosen as raw material to prepare porous carbon material(UlaC-950-HF) by the direct carbonization method without adding exogenous chemical activator. The result of analysis showed that the percentage of carbon in the sample was up to 93% and the product had a trend of part graphitizing. TGA result showed that the sample had high thermal stability(only 3% mass loss from 0 to 400 ℃). N₂ sorption isotherm results showed that the pore structure of porous carbon was mainly microporosity(maximal pore size distribution was 1.1 nm) with a small amount of mesoporous pore. The distribution of pore diameter was narrow. There were slit-like structures in the sample which were beneficial for storaging high-pressure methane. The capacity of methane storage of UlaC-950-HF was up to 208 mg/g(mass fraction, 17%) or volumetric capacity of 232 at 298 K and 3.5 MPa. This paper also explained the reason for the outstanding capacity of storaging high-pressure methane by drawing a theoretical model.

Key words: Carbonized biomass, Carex meyeriana Kunth, Self-activation, Methane storage

CLC Number:

O613.71

TrendMD:

WANG Yun, BEN Teng, QIU Shilun. Performance of Gas Storage in Carex meyeriana Kunth-based Carbon^†[J]. Chem. J. Chinese Universities, 2016, 37(5): 801.

Figures/Tables 12

References 42

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Type	Material	Surface area/ (m²·g^-1)	Pore volume/ (cm³·g^-1)	Condition		CH₄ storage capacity(%)	Excess CH₄ uptake/ (mL·mL^-1)	Heat of adsorption/ (kJ·mol^-1)	Ref.
Type	Material	Surface area/ (m²·g^-1)	Pore volume/ (cm³·g^-1)	10^-5p/Pa		CH₄ storage capacity(%)	Excess CH₄ uptake/ (mL·mL^-1)	Heat of adsorption/ (kJ·mol^-1)	T/K
Porous	COF-102	3620	1.55	35	298	15.8	120	8.6	[27]
polymers	COF-103	3530	1.54	35	298	14.9	152	9.5	[27]
	HCP-1	1904	0.54	15	298	6.4			[28]
	HCP-4	1366	0.55	36	298	8.1			[28]
	PIM-1	850	0.349	15	293	3.8			[29]
	PPN-3	2840	1.7	35	295	12.2		15.2	[30]
	PPN-4	6461	3.04	55	295	21.5			[31]
MOFs	Cu₂(sbtc)[PCN-11]	1931	0.91	25	298	14.0	171	14.6	[32]
	Cu₂(adip)[PCN-14]	1753	0.87	35	290	15.3	220	30	[32]
	Ni(dhtp)[NiMOF-74,CPO-27-Ni]	1027	0.54	35	298	11.9	206	21.5—22	[32]
	(Cu₃(btc)₂)[HKUST-1]	1502	0.82	35	304	10.2	204	18.7	[32]
	Zn₄O(bdc)₃[MOF-5]	1870		36	300	13.5	110	12.2	[32]
Zeolites	CaX		0.36	32	298	7.5		24.68	[33]
Porous	CMK-3	950	0.87	35	298	7.5		19.78	[34]
carbon	K-PAF-1-750	2926		35	298	17.1		17.9	[35]
	Maxsorb A	3100		40	298	16.4	152		[36]
	KUA31752	3355		40	298	15.6	155		[36]
	PC	1220	0.47	20	298	10.2	141		[36]
	Saran A carbon 36X	1650		32	298	11.5			[36]
	KF-1500	1500		32	298	7.6			[10]

Type	Material	Surface area/ (m²·g^-1)	Pore volume/ (cm³·g^-1)	Condition		CH₄ storage capacity(%)	Excess CH₄ uptake/ (mL·mL^-1)	Heat of adsorption/ (kJ·mol^-1)	Ref.
Type	Material	Surface area/ (m²·g^-1)	Pore volume/ (cm³·g^-1)	10^-5p/Pa		CH₄ storage capacity(%)	Excess CH₄ uptake/ (mL·mL^-1)	Heat of adsorption/ (kJ·mol^-1)	T/K
Porous	COF-102	3620	1.55	35	298	15.8	120	8.6	[27]
polymers	COF-103	3530	1.54	35	298	14.9	152	9.5	[27]
	HCP-1	1904	0.54	15	298	6.4			[28]
	HCP-4	1366	0.55	36	298	8.1			[28]
	PIM-1	850	0.349	15	293	3.8			[29]
	PPN-3	2840	1.7	35	295	12.2		15.2	[30]
	PPN-4	6461	3.04	55	295	21.5			[31]
MOFs	Cu₂(sbtc)[PCN-11]	1931	0.91	25	298	14.0	171	14.6	[32]
	Cu₂(adip)[PCN-14]	1753	0.87	35	290	15.3	220	30	[32]
	Ni(dhtp)[NiMOF-74,CPO-27-Ni]	1027	0.54	35	298	11.9	206	21.5—22	[32]
	(Cu₃(btc)₂)[HKUST-1]	1502	0.82	35	304	10.2	204	18.7	[32]
	Zn₄O(bdc)₃[MOF-5]	1870		36	300	13.5	110	12.2	[32]
Zeolites	CaX		0.36	32	298	7.5		24.68	[33]
Porous	CMK-3	950	0.87	35	298	7.5		19.78	[34]
carbon	K-PAF-1-750	2926		35	298	17.1		17.9	[35]
	Maxsorb A	3100		40	298	16.4	152		[36]
	KUA31752	3355		40	298	15.6	155		[36]
	PC	1220	0.47	20	298	10.2	141		[36]
	Saran A carbon 36X	1650		32	298	11.5			[36]
	KF-1500	1500		32	298	7.6			[10]