Chem. J. Chinese Universities ›› 2015, Vol. 36 ›› Issue (10): 2009.doi: 10.7503/cjcu20150207
• Physical Chemistry • Previous Articles Next Articles
LIANG Weiping, ZHAO Xiaohui, AN Dong, XU Qian, YE Zhiwen*()
Received:
2015-03-18
Online:
2015-10-10
Published:
2015-09-18
Contact:
YE Zhiwen
E-mail:yezw@njust.edu.cn
CLC Number:
TrendMD:
LIANG Weiping, ZHAO Xiaohui, AN Dong, XU Qian, YE Zhiwen. Synthesis and Surface Properties of Siloxane Gemini Imidazolium Surfactant†[J]. Chem. J. Chinese Universities, 2015, 36(10): 2009.
Surfactant | cmc/(mmol·L-1) | γcmc/(mN·m-1) | πcmc/(mN·m-1) | Гmax/(μmol·m-2) | pc20 | Amin /nm2 |
---|---|---|---|---|---|---|
[Si4-4-Si4im]Cl2 | 0.54 | 18.6 | 53.4 | 0.704 | 6.04 | 2.36 |
[C14-4-C14im]Cl2 | 0.27 | 39.5 | 32.5 | 0.811 | 4.47 | 2.05 |
[Si4mim]Cl[ | 7.4 | 20.4 | 52.1 | 0.84 | 5.43 | 1.98 |
Table 1 Adsorption parameters of the surfactants in aqueous solution at 298.15 K
Surfactant | cmc/(mmol·L-1) | γcmc/(mN·m-1) | πcmc/(mN·m-1) | Гmax/(μmol·m-2) | pc20 | Amin /nm2 |
---|---|---|---|---|---|---|
[Si4-4-Si4im]Cl2 | 0.54 | 18.6 | 53.4 | 0.704 | 6.04 | 2.36 |
[C14-4-C14im]Cl2 | 0.27 | 39.5 | 32.5 | 0.811 | 4.47 | 2.05 |
[Si4mim]Cl[ | 7.4 | 20.4 | 52.1 | 0.84 | 5.43 | 1.98 |
Fig.3 Specific conductivity as a function of concentration at different temperatures(A) [Si4-4-Si4im]Cl2; (B) [C14-4-C14im]Cl2. Temperature/℃: a. 15; b. 20; c. 25; d. 30; e. 35.
Surfactant | T/K | cmc/(mmol·L-1) | β | Δ | Δ | TΔ |
---|---|---|---|---|---|---|
[Si4-4-Si4im]Cl2 | 288.15 | 0.533 | 0.378 | -24.30 | -2.690 | 21.610 |
293.15 | 0.547 | 0.378 | -24.67 | -2.785 | 21.885 | |
298.15 | 0.557 | 0.373 | -24.89 | -2.862 | 22.028 | |
303.15 | 0.570 | 0.369 | -25.16 | -2.949 | 22.211 | |
308.15 | 0.580 | 0.358 | -25.21 | -3.008 | 22.202 | |
[C14-4-C14im]Cl2 | 288.15 | 0.265 | 0.609 | -32.56 | -4.571 | 27.989 |
293.15 | 0.273 | 0.614 | -33.17 | -4.750 | 28.420 | |
298.15 | 0.281 | 0.602 | -33.31 | -4.862 | 28.448 | |
303.15 | 0.282 | 0.588 | -33.42 | -4.963 | 28.457 | |
308.15 | 0.297 | 0.588 | -33.82 | -5.127 | 28.693 | |
[Si4mim]Cl[ | 288.15 | 6.6 | 0.32 | -28.64 | -40.48 | -11.84 |
293.15 | 6.9 | 0.30 | -28.42 | -44.39 | -15.97 | |
298.15 | 7.5 | 0.27 | -28.11 | -48.17 | -20.06 | |
303.15 | 8.2 | 0.25 | -27.71 | -51.82 | -24.11 | |
308.15 | 9.0 | 0.22 | -27.32 | -55.35 | -28.03 |
Table 2 Influence of temperature on the parameters of micellization for the surfactants in aqueous solution
Surfactant | T/K | cmc/(mmol·L-1) | β | Δ | Δ | TΔ |
---|---|---|---|---|---|---|
[Si4-4-Si4im]Cl2 | 288.15 | 0.533 | 0.378 | -24.30 | -2.690 | 21.610 |
293.15 | 0.547 | 0.378 | -24.67 | -2.785 | 21.885 | |
298.15 | 0.557 | 0.373 | -24.89 | -2.862 | 22.028 | |
303.15 | 0.570 | 0.369 | -25.16 | -2.949 | 22.211 | |
308.15 | 0.580 | 0.358 | -25.21 | -3.008 | 22.202 | |
[C14-4-C14im]Cl2 | 288.15 | 0.265 | 0.609 | -32.56 | -4.571 | 27.989 |
293.15 | 0.273 | 0.614 | -33.17 | -4.750 | 28.420 | |
298.15 | 0.281 | 0.602 | -33.31 | -4.862 | 28.448 | |
303.15 | 0.282 | 0.588 | -33.42 | -4.963 | 28.457 | |
308.15 | 0.297 | 0.588 | -33.82 | -5.127 | 28.693 | |
[Si4mim]Cl[ | 288.15 | 6.6 | 0.32 | -28.64 | -40.48 | -11.84 |
293.15 | 6.9 | 0.30 | -28.42 | -44.39 | -15.97 | |
298.15 | 7.5 | 0.27 | -28.11 | -48.17 | -20.06 | |
303.15 | 8.2 | 0.25 | -27.71 | -51.82 | -24.11 | |
308.15 | 9.0 | 0.22 | -27.32 | -55.35 | -28.03 |
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