Analysis of Binding Properties Between β-Cyclodextrin Bipyridine-ruthenium Derivative and Vitamins by Their Fluorescence Spectra

doi:10.7503/cjcu20130077

Chem. J. Chinese Universities ›› 2013, Vol. 34 ›› Issue (7): 1606.doi: 10.7503/cjcu20130077

• Analytical Chemistry • Previous Articles Next Articles

Analysis of Binding Properties Between β-Cyclodextrin Bipyridine-ruthenium Derivative and Vitamins by Their Fluorescence Spectra

ZHENG Shan-Shan, CHEN Hong, QI Yan-Tao, WANG Xiu-Hua, FAN Hua-Jun, ZHAO Ying-Ying, ZHANG Fan, YANG Fan, TANG Jie, HE Pin-Gang

Department of Chemistry, East China Normal University, Shanghai 200062, China

Received:2013-01-22 Online:2013-07-10 Published:2013-06-21
Contact: Pingang E-mail:pghe@chem.ecnu.edu.cn

Abstract

Abstract:

This paper presents a research of the binding interaction of a new synthetized β-cyclodextrin bipyridine-ruthenium derivative[β-CD-Ru(bpy)₃] with a series of vitamins using fluorescent spectrometry. The performance of fluorescence emission of β-CD-Ru(bpy)₃ was excellent due to the existence of the center of bipyridine-ruthenium. Based on the effect of molecular recognition between β-cyclodextrin and guest molecule, the fluorescence quenching occured because of the energy transfer between the β-CD-Ru(bpy)₃ and the vitamin when a kind of vitamin was added. According to the quantitative value of fluorescence quenching, the binding constants of the new derivative with respect to various vitamins were determined by Benesi-Hildebrand Equation. The results show that the binding capacities of the vitamins with β-CD-Ru(bpy)₃ were in a descending sequence of VB₁₂>VK₃>VC>VA.

Key words: β-Cyclodextrin bipyridine-ruthenium derivative, Vitamin, Fluorescence spectra, Binding interaction

CLC Number:

O657

TrendMD:

ZHENG Shan-Shan, CHEN Hong, QI Yan-Tao, WANG Xiu-Hua, FAN Hua-Jun, ZHAO Ying-Ying, ZHANG Fan, YANG Fan, TANG Jie, HE Pin-Gang. Analysis of Binding Properties Between β-Cyclodextrin Bipyridine-ruthenium Derivative and Vitamins by Their Fluorescence Spectra[J]. Chem. J. Chinese Universities, 2013, 34(7): 1606.

References

Related Articles 15

[1]	WANG Bin,WANG Xiaohong,DUAN Limei,XU Liang,ZHAO Peng,JIAN Jinpeng,LIU Zongrui. Spectral Detection for Vitamin C and H₂O₂ Based on the Reversible Color Change and Luminescent Switching Properties of P₂Mo₁₈ $O 62 6 -$ @Tb³⁺ Mixed Solution^† [J]. Chem. J. Chinese Universities, 2019, 40(4): 676.
[2]	LI Wenwen, ZHU Airu, LONG Yijing, WANG Chunyan, HAN Yuanping, DUAN Yixiang. Metabolomics Study of Serum and Liver in Type 2 Diabetes Mice Induced by High Fat Diet with Vitamin D Deficiency^† [J]. Chem. J. Chinese Universities, 2018, 39(11): 2395.
[3]	CUI Zhi-Ping, LIU Shao-Pu, LIU Zhong-Fang, HU Xiao-Li. Dual-wavelength Overlapping Resonance Rayleigh Scattering Spectra of the Interactions of Vitamin B₁₂ with 12-Tungstophosphoric Acid and Their Analytical Applications [J]. Chem. J. Chinese Universities, 2012, 33(10): 2205.
[4]	SONG Zhen, ZHENG Xiao-Yan, PANG Er-Guo, YANG Bin-Sheng*. Spectral Studies on the Interaction Between VB₆ and Various CopC [J]. Chem. J. Chinese Universities, 2011, 32(7): 1456.
[5]	FENG Feng, CHEN Ze-Zhong, LIN Jie-Diao. Application of the Combination of the Drops Fluorimetry Sensor with the Computer in the Microanalysis [J]. Chem. J. Chinese Universities, 2004, 25(S1): 82.
[6]	WANG Xue-Liang, SUN Wei, JIAO Kui, ZHANG Kui-Tang . Determination of Serum Albumin Using Bromocresol Purple as Electrochemical Probe [J]. Chem. J. Chinese Universities, 2004, 25(8): 1448.
[7]	ZHANG Jian-Yun, HUANG Long-Quan, HAYAKAWA Takashi, TSUGE Haruhito. Analysis of Vitamin B₆ Derivatives in Biological Samples with High Performance Liquid Chromatography [J]. Chem. J. Chinese Universities, 2004, 25(4): 638.
[8]	WANG Qun, NI Jia-Zuan, . Effect of Lanthanides on the Interaction Between Recombinant Endostatin and Heparin [J]. Chem. J. Chinese Universities, 2004, 25(10): 1783.
[9]	FENG Ya-Qing, ZHANG Xiao-Dong, MENG Shu-Xian, ZHOU Li-Shan . Synthesis of a Dimer-VB₁₂ Model Molecule and Stability of Co-N Bond [J]. Chem. J. Chinese Universities, 2003, 24(6): 1031.
[10]	GUO Can-Cheng, LI He-Ping, ZHANG Xiao-Bing, TONG Rong-Biao . Synthesis of meso-5,10,15,20-Tetra[4-(N-pyrrolidinyl)phenyl] Porphyrin and Its Interaction with Bovine Serum Albumin [J]. Chem. J. Chinese Universities, 2003, 24(2): 282.
[11]	QI Yun-Peng, WU Yu-Tian, LI Tong-Hua, HUANG Jian-Rong, WU Xiang-Feng, CHAI Yi-Feng . Application of Orthogonal Projection-based Algorithms and HLAE in the Analysis of Grey System [J]. Chem. J. Chinese Universities, 2003, 24(11): 1976.
[12]	CHEN Fen-Er, FU Han, MENG Ge, LUO You-Fu, YAN Ming-Guo . Studies on the Asymmetric Total Synthesis of d-Biotin(Ⅴ) [J]. Chem. J. Chinese Universities, 2002, 23(6): 1060.
[13]	CHEN Fen-Er, LING Xiu-Hong, LÜ Yin-Xiang, ZHANG Xiao-Yue, PENG Xiao-Hua . Studies on the Asymmetry Total Synthesis of d-Biotin(Ⅱ) [J]. Chem. J. Chinese Universities, 2001, 22(7): 1141.
[14]	WANG Chao-Yang, SUN Qi-Long, TONG Zhen, LIU Xin-Xing, ZENG Fang, GAO Feng . Binding of Ionic Derivative of Pyrene to Strong Polyelectrolyte [J]. Chem. J. Chinese Universities, 2001, 22(7): 1265.
[15]	WANG Heng-Shan, JIA Qiang, YANG Xiao-Wu, WANG Rui . Studies on the Asymmetric Synthesis of Precursor of Vitamin B₁₂ Ring-B Imide and Succinimide Drugs [J]. Chem. J. Chinese Universities, 2000, 21(3): 391.

Analysis of Binding Properties Between β-Cyclodextrin Bipyridine-ruthenium Derivative and Vitamins by Their Fluorescence Spectra

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments