Synthesis and Property of Nano-sized Mn-ZSM-5 Zeolite via One-step Hydrothermal Method

doi:10.3969/j.issn.0251-0790.2012.03.004

Abstract

Abstract:

High pure Mn-ZSM-5 zeolite was synthesized through one-step hydrothermal method by direct introduction of divalent manganese source under strong alkaline condition. The samples were characterized by XRD, FTIR, ²⁹Si NMR, SEM, ICP and N₂ adsorption-desorption techniques. The results indicated that manganese irons were incorporated into the zeolite skeleton. Using styrene oxidation as a probe reaction, H₂O₂ as the oxidant and Mn-ZSM-5 as the catalyst, the conversion of styrene reached 84.98%, turnover number was 208, styrene epoxide selectivity and yield was about 87.62% and 74.46%, respectively.The synthesized nano sized Mn-ZSM-5 is a promising catalyst for oxidation reactions.

Key words: Mn-ZSM-5 zeolite, Strong alkaline, Hydrothermal synthesis, Styrene oxidation

CLC Number:

O614

TrendMD:

ZHANG Qian, CHEN Chun-Ying, DING Shuang, ZHANG Wen-Ting, XU Di-Ou, TANG Xiao-Jian, WANG Run-Wei, JIANG Ri-Hua, ZHANG Zong-Tao, QIU Shi-Lun. Synthesis and Property of Nano-sized Mn-ZSM-5 Zeolite via One-step Hydrothermal Method[J]. Chem. J. Chinese Universities, 2012, 33(03): 453.

References

[1] Taramasso M., Perogo G., Notari B.. Preparation of Porous Crystalline Synthetic Materials Comprised of Silicon and Titanium Oxides, US 4410501, 1983-10-18
[2] Tessonnier J. P., Louis B., Rigolet S., Ledoux M. J., Cuong P. H.. Applied Catalysis A: General[J], 2008, 336: 79-88
[3] Jin T. H., Hwang Y. K., Hong D. Y., Jhung S. H., Hwang J. S., Park S. E., Kim Y. H., Chang J. S.. Research on Chemical Intermediates[J], 2007, 33: 501-512
[4] Yanga G. H., Hea J. J., Yoneyamaa Y., Tanb Y., Hanb Y., Tsubaki N.. Applied Catalysis A: General[J], 2007, 329: 99-105
[5] Yang P. P., Shang Y. C., Wang J., Yu J. F., Wu T. H.. Reaction Kinetics and Catalysis Letters[J], 2007, 91: 391-398
[6] Iglesiaa D. L. O., Sebastiána V., Malladaa R., Nikolaidisb G., Coronasa J., Kolbb G., Zapfb R., Hesselb V., Santamaría J.. Catalysis Today[J], 2007, 125: 2-10
[7] Valkaj K. M., Katovic A., Zrncevic S.. J. Hazard. Mater.[J], 2007, 144: 663-667
[8] Round C. I., Williams C. D., Latham K., Catherine V. A. D.. Chem. Mater.[J], 2001, 13(2): 468-472
[9] Mhamdi M., Khaddar S., Ghorbel A.. Applied Catalysis A: General[J], 2008, 337: 39-47
[10] Tacolaro A., Tacolaro P., Driolia E.. Journal of Crystal Growth[J], 2006, 289: 609-616
[11] LV Xin-Chun(吕新春), ZHAO Rong(赵荣), WU Tai-Shu(吴泰琉), SUN Yao-Jun(孙尧俊), TANG Yi(唐颐). Chem. J. Chinese Universities(高等学校化学学报)[J], 2011, 32(3): 494-496
[12] SHI Chuan(石川), CHENG Mo-Jie(程谟杰), QU Zhen-Ping(曲振平). Chem. J. Chinese Universities(高等学校化学学报)[J], 2002, 23(4): 628-631
[13] Rane N., Kersbulck M., Santen R. A. V., Hensen E. J. M.. Microp. Mesop. Mater.[J], 2008, 110: 279-291
[14] Jia J., Pillai K. S., Sachtler W. M. H.. Journal of Catalysis[J], 2004, 221: 119-126
[15] LI Zhe(李哲), CHEN Bing(陈兵), HUANG Wei(黄伟), XIE Ke-Chang(谢克昌). Chem. J. Chinese Universities(高等学校化学学报)[J], 2006, 27(10) : 1907-1911
[16] Mhamdi M., Khaddar S., Ghorbel A.. Applied Catalysis A: General[J], 2008, 337: 39-47
[17] ZHANG Chun-Lei(张春雷), WU Zhi-Yun(吴志芸). Chem.J.Chinese Universities(高等学校化学学报)[J], 1994, 15(11): 1670-1674
[18] Milanesio M., Lamberti C., Aiello R., Testa F., Piana M., Viterbo D.. J. Phys. Chem. B[J], 2000, 104: 9951-9953
[19] Zhang Y. H., Briggs D. N., Smit E. D., Bell A. T.. Journal of Catalysis[J], 2007, 251: 443-452
[20] Phiriyawirut P., Jamieson A. M., Wongkasem J. S.. Microp. Mesop. Mater.[J], 2005, 77: 203-213
[21] Ko Y. S., Jang H. T., Ahn W. S., Korean J.. Chemistry Engineering[J], 2008, 25: 1286-1291
[22] Younghee K., Kim S. J., Kim M. H., Park J. H., Parise J. B., Young S. U.. Microp. Mesop. Mater.[J], 1999, 30: 213-218
[23] Lee B., Ma Z., Zhang Z. T., Park C., Dai S.. Microp. Mesop. Mater.[J], 2009, 122: 160-167
[24] Flanigen E. M., Kbataini H., Szymaski H. A.. Adv. Chem. Ser.[J], 1971, 101: 249-254
[25] Miecznikowski A., Hanuza J.. Zeolites[J], 1987, 12: 201-206
[26] Round C. I., Williams C. D., Catherine V. A. D.. Chem. Commun.[J], 1997: 1849-1850
[27] Sun X. Y., Jiao W., Xiang S. G.. Chem. Res. Chinese Universities[J], 2011, 27(2): 318-323