高等学校化学学报

高等学校化学学报 ›› 1995, Vol. 16 ›› Issue (8): 1306.

• 论文 • 上一篇    下一篇

α-蒎烯/苯乙烯共聚产物微臭氧化-薄层层析分离研究

邓云祥, 彭超盼, 刘平, 张仁俊, 曾陇梅   

  1. 中山大学化学系, 广州, 510275
  • 收稿日期:1994-11-23 修回日期:1995-03-01 出版日期:1995-08-24 发布日期:1995-08-24
  • 通讯作者: 邓云祥,男,59岁,教授.
  • 作者简介:邓云祥,男,59岁,教授.
  • 基金资助:

    国家自然科学基金;广东省科学基金

Studies on the Microozonization-TLC Method for the Separation and Analysis of Copolymerization Products of α-Pinene/Styrene

DENG Yun-Xiang, PENG Chao-Pan, LIU Ping, ZHANG Ren-Jun, ZENG Long-Mei   

  1. Department of Chemistry, Zhongshan University, Guangzhou, 510275
  • Received:1994-11-23 Revised:1995-03-01 Online:1995-08-24 Published:1995-08-24

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摘要： 建立了一种α-蒎烯/苯乙烯共用产物分离分析微臭氧化-薄层层析法。通过标准样品的分离和IR、NMR表征以及共聚体组分的测定,表明这种方法对α-蒎烯/苯乙烯均聚体混合物和共聚产物中均、共聚体的分离完全,样品回收率很高,解决了α-蒎烯/苯乙烯均、共聚体无法分离分析的难题。

关键词: 臭氧化法, 薄层层析法, 共聚物的分离分析, &alpha, -蒎烯/苯乙烯共聚体

Abstract: The microozonization-thin layer chromatography(TLC)method for the separation and analysis of copolymerization products of α-pinene/styrene has been established.It is the process that the copolymerization products is ozonized first under condition of selective and quantitative ozonization of endo-double bond in the sample;and then the ozonide obtained is separated into two samples of insoluble and soluble part in methanol;further,both of the two samples are separated with the TLC respectively into two parts,and four fractions which are an ozonized poly(α-pinene),two types of ozoni zed copolymers of α-pinene/styrene and a poly(styrene)are collected with the way in Fig.1.Characterized results have been obtained by IR,NMR,MS and GPC evidencing that the homopolymer and the copolymer can be separated from the copolymerization product fully,and components in the copolymer can be determined in precise terms.

Key words: Ozonization method, Thin layer chromatography method, Separation and analysis of copolymer, Copolymer of α-pinene/styrene

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