高等学校化学学报 ›› 2000, Vol. 21 ›› Issue (1): 45.

• 论文 • 上一篇    下一篇

富勒烯烟炱的吸附性及其在大气挥发性有机物分析中的应用

陈建新1, 陈才1, 盛国英1, 王新明2, 傅家谟2   

  1. 1. 中国科学院广州地球化学研究所有机地球化学国家重点实验室, 广州 510640;
    2. 中国科学院长春应用化学研究所, 长春 130022
  • 收稿日期:1999-05-05 出版日期:2000-01-24 发布日期:2000-01-24
  • 通讯作者: 盛国英(1935年出生),女,研究员,主要从事有机地球化学研究.
  • 基金资助:

    国家自然科学基金(批准号:49632060及49675271)资助

Adsorption Characteristics of Fullerene-extracted Soots and Its Application for Collecting Volatile Organic Compounds in Ambient Air

CHEN Jian-Xin1, CHEN Cai1, SHENG Guo-Ying1, WANG Xin-Ming2, FU Jia-Mo2   

  1. 1. State Key Laboratory of Organic Geochemistry, Gruangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640, China;
    2. Changchun Instituteof App lied Chemistry, Chinese Academy of Sciences, Changchun 130022, China
  • Received:1999-05-05 Online:2000-01-24 Published:2000-01-24

摘要: 研究了富勒烯烟炱对挥发性有机物(VOCs)的吸附作用.17种VOCs气体在烟炱上的比保留体积Vg20为17.4~2634L/g.富勒烯烟炱充填的吸附管对VOCs气体的吸附-热脱附回收率在40.8%~117%之间,大部分为(100±20)%.结果表明,富勒烯烟炱能够用于吸收和富集大气中痕量的VOCs

关键词: 挥发性有机物(VOCs), 吸附剂, 富勒烯烟炱

Abstract: Fullerene-extracted soots which are the by-product of producing fullerenes(C60/C70) can adsorb organic vapors efficiently. Breakthrough volumes(maximum sample volumes, Vmax)and specific retention volumes(20 ℃)of 17 VOCs(volatile organic compounds)are measured. The recoveries of adsorption/thermal desorption of Fullerene-extracted soots adsorbent tubes ranged from 40.8% to 117%, most of which are (100±20)%. Fullerene-extracted soots is cheap and can be used in environmental analysis for trapping and enriching traces of VOCs in ambient air.

Key words: Volatile organic compounds(VOCs), Adsorbent, Fullerene-extracted soots

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