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水凝胶体系交联过程织构变化的流变学研究

王刚1, 许元泽1, 范学勍1, 曹绪龙2, 刘坤2, 张继超2   

    1. 复旦大学高分子科学系, 聚合物分子工程教育部重点实验室, 上海 200433;
    2. 中国石化胜利油田有限公司地质科学研究院, 东营 257015
  • 收稿日期:2007-12-18 修回日期:1900-01-01 出版日期:2008-09-10 发布日期:2008-09-10
  • 通讯作者: 许元泽

Texture and Rheology of the Gelation Process of HPAM Aqueous Solution

WANG Gang1, XU Yuan-Ze1*, FAN Xue-Qin1, CAO XU-Long2, LIU Kun2, ZHANG Ji-Chao2   

    1. Key Laboratory of Molecular Engineering of Polymers of Ministry of Education, Department of Macromolecular Science, Fudan University, Shanghai 200433, China;
    2. Geological Scientific Research Institute of Shengli Oilfield, SINOPEC, Dongying 257015, China
  • Received:2007-12-18 Revised:1900-01-01 Online:2008-09-10 Published:2008-09-10
  • Contact: XU Yuan-Ze

摘要: 研究了由部分水解聚丙烯酰胺水溶液交联得到的用于三次采油的弱凝胶体系, 使用不同交联剂的水凝胶体系表现出不同的流变特性, 反映两种不同织态结构的弱凝胶, 一种为接近于均匀分形交联网的整体凝胶, 另一种为有特征尺度的非均匀交联网的胶态分散凝胶. 上述结果得到了光学显微镜观测的证明. 强剪切和拉伸流的结果表明, 当凝胶体系中存在大量胶团时, 强剪切可以加强体系中网络结构的完整性, 使得流变性质加强, 不同于一般凝胶的减弱趋势.

关键词: 水解聚丙烯酰胺, 弱凝胶, 流变性, 凝胶织构, 拉伸黏度

Abstract: The weak gels based on partial hydrolyzed polyacrylamide(HPAM) aqueous solutions gelated by organic crosslinkers were investigated rheologically with application background of tertiary oil recovery. The linear and non-linear rheological properties in gelation processes of weak gels with different crosslinkers reveal two kinds of textures near the gel point, one is a fractal network, and the other is a heterogeneous network with a characteristic dimension. The optical microscopic approved the rheological arguments. High shearing and the stretch flow in converging outlet measurements indicat that contrary to the static colloidal gels, the strong flows can reinforce the integrities of network structures and enhance the rheological properties. The potential in the EOR applications are also discussed.

Key words: Hyalrolyzed polyarylamide, Weak gel, Rheology, Gel texture, Elongational viscosity

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