高等学校化学学报

高等学校化学学报 ›› 2012, Vol. 33 ›› Issue (04): 823.doi: 10.3969/j.issn.0251-0790.2012.04.031

• 高分子化学 • 上一篇    下一篇

电子束固化含氟聚氨酯丙烯酸酯的制备与性能

徐海涛1, 李京1, 梁红波1, 熊磊1, 高歌2   

  1. 1. 南昌航空大学材料学院高分子材料与工程系, 南昌 330063;
    2. 吉林大学化学学院, 长春 130023
  • 收稿日期:2011-06-24 出版日期:2012-04-10 发布日期:2012-04-10
  • 作者简介:徐海涛, 男, 博士, 讲师, 主要从事功能涂层研究. E-mail: htxu1982@yahoo.com.cn
  • 基金资助:

    国家自然科学基金(批准号: 51103069)、江西省教育厅基金(批准号: GJJ10722)和南昌航空大学科研项目(批准号: 201001033)资助.

Synthesis and Properties of Fluorine-Containing Electron Beam Curing Polyurethane Acrylate

XU Hai-Tao1, LI Jing1, LIANG Hong-Bo1, XIONG Lei1, GAO Ge2   

  1. 1. Department of Polymer Materials and Engineering, College of Materials Science, Nanchang Hangkong University, Nanchang 330063, China;
    2. College of Chemistry, Jilin University, Changchun 130023, China
  • Received:2011-06-24 Online:2012-04-10 Published:2012-04-10
  • Supported by:

    国家自然科学基金(批准号: 51103069)、江西省教育厅基金(批准号: GJJ10722)和南昌航空大学科研项目(批准号: 201001033)资助.

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被引次数

10

摘要： 以六亚甲基二异氰酸酯三聚体、丙烯酸羟乙酯及羟基含氟丙烯酸酯为原料制备了电子束固化含氟聚氨酯丙烯酸酯预聚物. 通过傅里叶变换红外光谱(FTIR)和核磁共振氢谱(1H NMR)对产物进行了表征. 研究了产物与溶剂组成的两相混合体系的流变性能、电子束固化行为及固化后涂层性能. 结果表明, 产物与溶剂混合体系具有正触变性, 绝对黏度变化符合Sedden公式, 黏流活化能约为44.8 kJ/mol. 电子束固化后涂层性能(如热稳定性、硬度、附着力和光泽度)优良.

关键词: 电子束固化, 含氟聚氨酯丙烯酸酯, 流变性能

Abstract: The fluorine-containing electron beam curing polyurethane acrylate was prepared by hexamethy-lene diisocyanate triplolymer, hydroxyethyl acrylate and hydroxyl fluorine-containing acrylate. The expected products were proved by FTIR and 1H NMR. The rheological properties of the two-phase mixed system of the product and solvent, electron beam curing behavior and the properties of the cured coating were studied. The results show that the thixotropy of the mixed system has positive thixotropy, the absolute viscosity follows Sedden formula, and the viscous flow activation energy is about 44.8 kJ/mol. Electron beam cured coating has fine thermal stability, hardness, adhesion and glossiness.

Key words: Electron beam cured coating, Fluorine-containing polyurethane acrylate, Rheological property

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