有机亚碘酰化合物的研究(Ⅱ)—羧基及酯基取代亚碘酰芳烃的结构与性能的研究

高等学校化学学报 ›› 1986, Vol. 7 ›› Issue (10): 895.

有机亚碘酰化合物的研究(Ⅱ)—羧基及酯基取代亚碘酰芳烃的结构与性能的研究

朱申杰, 张春豪, 谭海安, 王平保

南开大学化学系

收稿日期:1985-06-10 出版日期:1986-10-24 发布日期:1986-10-24
基金资助:
中国科学院科学基金

Study on Organo Iodosocompounds(Ⅱ)—The Study of the Structures and Properties of Some lodosoaromatic Acids and Esters

Zhu Shenjie, Zhang Chunhao, Tan Haian, Wang Pingbao

Department of Chemistry, Nankai University, Tianjin

Received:1985-06-10 Online:1986-10-24 Published:1986-10-24

摘要/Abstract

摘要： 本文对邻亚碘酰肉桂酸、邻亚碘酸苯乙酸、邻亚碘酰苯甲酸及其酯和间亚碘酰笨甲酸进行了波谱分析,认为它们都存在着分子内成环结构。

Abstract: Ortho-Iodosocinnamic acid,ortho-iodosophenylacetic acid,and some ortho-lodosobenzoic esters(methyl,ethyl,isopropyl and tcrt-butyl estcrs)werc synthesized.By comparing their IRand NMRspectra with corresponding iodo compounds and iododichlorides,the intramolecular cyclic structure of these compounds was suggested.According to the IRspectra of ortho-,meta-and para-iodosobenzoic acids and esters,and by comparing their relative activities of oxygenalion of cyclohexane catalyzed by TPPFe(Ⅲ)Cl or TPPMn(Ⅲ)C1the intramolecular cyclic structures of ortho-iodosobenzoic acid and ester were suggested,too.This cyclic structure should form partially in meta-iodosobenzoic acid.

TrendMD:

朱申杰, 张春豪, 谭海安, 王平保. 有机亚碘酰化合物的研究(Ⅱ)—羧基及酯基取代亚碘酰芳烃的结构与性能的研究. 高等学校化学学报, 1986, 7(10): 895.

Zhu Shenjie, Zhang Chunhao, Tan Haian, Wang Pingbao . Study on Organo Iodosocompounds(Ⅱ)—The Study of the Structures and Properties of Some lodosoaromatic Acids and Esters. Chem. J. Chinese Universities, 1986, 7(10): 895.