高等学校化学学报 ›› 1986, Vol. 7 ›› Issue (10): 895.
• 研究论文 • 上一篇 下一篇
朱申杰, 张春豪, 谭海安, 王平保
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中国科学院科学基金
Zhu Shenjie, Zhang Chunhao, Tan Haian, Wang Pingbao
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摘要: 本文对邻亚碘酰肉桂酸、邻亚碘酸苯乙酸、邻亚碘酰苯甲酸及其酯和间亚碘酰笨甲酸进行了波谱分析,认为它们都存在着分子内成环结构。
Abstract: Ortho-Iodosocinnamic acid,ortho-iodosophenylacetic acid,and some ortho-lodosobenzoic esters(methyl,ethyl,isopropyl and tcrt-butyl estcrs)werc synthesized.By comparing their IRand NMRspectra with corresponding iodo compounds and iododichlorides,the intramolecular cyclic structure of these compounds was suggested.According to the IRspectra of ortho-,meta-and para-iodosobenzoic acids and esters,and by comparing their relative activities of oxygenalion of cyclohexane catalyzed by TPPFe(Ⅲ)Cl or TPPMn(Ⅲ)C1the intramolecular cyclic structures of ortho-iodosobenzoic acid and ester were suggested,too.This cyclic structure should form partially in meta-iodosobenzoic acid.
TrendMD:
朱申杰, 张春豪, 谭海安, 王平保. 有机亚碘酰化合物的研究(Ⅱ)—羧基及酯基取代亚碘酰芳烃的结构与性能的研究. 高等学校化学学报, 1986, 7(10): 895.
Zhu Shenjie, Zhang Chunhao, Tan Haian, Wang Pingbao . Study on Organo Iodosocompounds(Ⅱ)—The Study of the Structures and Properties of Some lodosoaromatic Acids and Esters. Chem. J. Chinese Universities, 1986, 7(10): 895.
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http://www.cjcu.jlu.edu.cn/CN/Y1986/V7/I10/895