高等学校化学学报 ›› 1988, Vol. 9 ›› Issue (1): 9.
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俞运鹏, 徐正, 游效曾
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Yu Yunpeng, Xu Zheng, You Xiaozeng
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摘要: 本文报道了用气液色谱法测定不同温度下,酸碱加合反应: .实验数据可以用公式:lgK=-5.196(±0.328)+[1.6503(0.1144)/T]×103来描述。
Abstract: It is reported that the equilibrium constants of acid-base interaction between Ni(C8H17O)2PS2]2, and (C2H5)3Nforming 1:1 adduct were determined by GLCmethod at variable temperature. Thermodynamic parameters △Hand △Swere found. The experimental data fit the equation:lgK=-5.196(±0.328)+[1.6503(0.1144)/T]×103。
TrendMD:
俞运鹏, 徐正, 游效曾. 气液色谱法测定双-(O,O′-二正辛基二硫代磷酸酯)合镍(Ⅱ)和三乙胺加合反应的热力学参数. 高等学校化学学报, 1988, 9(1): 9.
Yu Yunpeng, Xu Zheng, You Xiaozeng . Determination of Thermodynamic Parameters of Adduct Reaction of Nic(O8H17O)2PS2]2 and (C2H5)3N by GLC Method. Chem. J. Chinese Universities, 1988, 9(1): 9.
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