高等学校化学学报

高等学校化学学报 ›› 1988, Vol. 9 ›› Issue (1): 9.

• 论文 • 上一篇    下一篇

气液色谱法测定双-(O,O′-二正辛基二硫代磷酸酯)合镍(Ⅱ)和三乙胺加合反应的热力学参数

俞运鹏, 徐正, 游效曾   

  1. 南京大学配位化学研究所
  • 收稿日期:1986-08-12 出版日期:1988-01-24 发布日期:1988-01-24

Determination of Thermodynamic Parameters of Adduct Reaction of Nic(O8H17O)2PS2]2 and (C2H5)3N by GLC Method

Yu Yunpeng, Xu Zheng, You Xiaozeng   

  1. Coordination Chemistry Institute, Nanjing University, Nanjing
  • Received:1986-08-12 Online:1988-01-24 Published:1988-01-24

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摘要： 本文报道了用气液色谱法测定不同温度下,酸碱加合反应:  .实验数据可以用公式:lgK=-5.196(±0.328)+[1.6503(0.1144)/T]×103来描述。

Abstract: It is reported that the equilibrium constants of acid-base interaction between Ni(C8H17O)2PS2]2, and (C2H5)3Nforming 1:1 adduct were determined by GLCmethod at variable temperature. Thermodynamic parameters △Hand △Swere found. The experimental data fit the equation:lgK=-5.196(±0.328)+[1.6503(0.1144)/T]×103。

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