高等学校化学学报

高等学校化学学报 ›› 1990, Vol. 11 ›› Issue (12): 1340.

• 研究论文 • 上一篇    下一篇

脉冲极谱法研究(Ⅳ)——示差脉冲极谱吸附可逆波理论和验证

张剑荣, 张祖训   

  1. 南京大学化学系, 210008
  • 收稿日期:1990-07-11 出版日期:1990-12-24 发布日期:1990-12-24
  • 通讯作者: 张祖训

Investigation on Pulse Polarography(Ⅳ)——Theory and Verification for Reversible Wave of Differential Pulse Polarography Influenced by Adsorption

Zhang Jian-rong, Zhang Zu-xun   

  1. Department of Chemistry, Nanjing University, Nanjing, 210008
  • Received:1990-07-11 Online:1990-12-24 Published:1990-12-24

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摘要： 本文推导出同时受反应物和产物吸附影响的示差脉冲极谱可逆波方程式,并讨论了电流和电位的性质。实验结果表明该方程满意地描述了实验曲线。

关键词: 示差脉冲极谱, 吸附可逆波, 极谱理论

Abstract: An equation and its current-potential charaters of differential pulse polarography for reversible waves influenced simultaneously by, the adsorption of both reactant and product are presented and discussed in this paper. The results obtained are the same as those calculated by numerical solution. Teste are carried out to verify the equation by using three systems. The curves described by the theory are in good agreement with the experimental results.

Key words: Differential pulse polarography, Adsorptive reversible wave, Polarography theory

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