高等学校化学学报

高等学校化学学报 ›› 2011, Vol. 32 ›› Issue (7): 1656.

• 研究论文 • 上一篇    

复合乳化剂微乳液法制备聚苯胺及其电化学性能

马利, 贾春悦, 甘孟瑜, 郝少娜, 刘兴敏, 李志春   

  1. 重庆大学化学化工学院, 重庆 400030
  • 收稿日期:2010-07-31 修回日期:2010-12-16 出版日期:2011-07-10 发布日期:2011-06-02
  • 通讯作者: 马利 E-mail:mlsys607@126.com
  • 基金资助:

     国家自然科学基金(批准号： 20176066)资助.

Synthesis and Electrochemical Behavior of Polyainiline by Composite Emulsifier Microemulision Polymerization

MA Li*, JIA Chun-Yue, GAN Meng-Yu, HAO Shao-Na, LIU Xing-Min, LI Zhi-Chun   

  1. College of Chemistry & Chemical Engineering, Chongqing University, Chongqing 400030, China
  • Received:2010-07-31 Revised:2010-12-16 Online:2011-07-10 Published:2011-06-02
  • Contact: Ma Li E-mail:mlsys607@126.com
  • Supported by:

     国家自然科学基金(批准号： 20176066)资助.

PDF (PC)

被引次数

14

摘要： 采用复合乳化剂微乳液法合成了导电聚苯胺(PANI)，以碳纸负载PANI为工作电极，考察了十二烷基苯磺酸钠(SDBS)和聚乙二醇辛基苯基醚(TX-100)的配比及其复合乳化剂(E)和氧化剂(APS)用量对复合乳化剂微乳液法合成PANI电化学性能(循环伏安、塔费尔)的影响；通过对产物电导率和产率的对比分析，印证了PANI电化学性能表征结果的有效性。结果表明：当SDBS与TX-100的质量比为1/2，E与苯胺(An)单体的质量比为5/3，APS与An的摩尔比为1.2时，PANI的各项性能指标达到最好，且产物的循环伏安峰电流、腐蚀电位和电导率均高于单组分乳化剂SDBS或TX-100微乳液法制备的PANI。

关键词: 聚苯胺, 微乳液, 复合乳化剂, 电化学性能

Abstract: The polyaniline(PANI) was prepared by microemulsion polymerization in the presence of composite emulsifier. The effects of the mass ratio of sodium dodecylbenzenesulfonate (SDBS) to Triton X-100(TX-100) and the amout of composite emulsifier(E) and oxidant(APS) on the electrochemical properties(cyclic voltammogram, tafel) of PANI were discussed via cyclic voltammogram (CV) using the carbon paper loaded PANI as working electrode, and the characterization result of the electrochemical properties of the PANI was also proved by the contrast analysis of the conductivity and yield of PANI. The experimental results showed that when the mass ratio of SDBS to TX-100 and E to anilin(An) was 1/2 and 5/3, the molar ratio of APS to An was 1.2, the properties of the PANI were the best; besides, the peak current of CV, the corrosion potential and conductivity of product were higher than PANI synthsized by microemulsion polymerization in the presence of single emulsifier (SDBS or TX-100).

Key words: Polyaniline, Microemulsion, Composite emulsifier, Electrochemical properties

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