生物分子辅助溶剂热合成硫化锑纳米棒

高等学校化学学报 ›› 2010, Vol. 31 ›› Issue (7): 1303.

生物分子辅助溶剂热合成硫化锑纳米棒

钟家松¹, 向卫东^1,2, 刘丽君¹, 杨昕宇¹, 蔡文², 张景峰¹, 梁晓娟¹

1. 温州大学化学与材料工程学院, 温州 325035;
2. 同济大学材料科学与工程学院, 上海 200092

收稿日期:2009-11-16 出版日期:2010-07-10 发布日期:2010-07-10
通讯作者: 向卫东, 男, 博士, 教授, 博士生导师, 主要从事无机非金属纳米材料的制备和LED的研究. E-mail: weidongxiang@yahoo.com.cn
基金资助:
国家自然科学基金(批准号: 50772075, 50972107)资助.

Biomolecule-assisted Solvothermal Synthesis of Sb₂S₃ Nanorods

ZHONG Jia-Song¹, XIANG Wei-Dong^1,2*, LIU Li-Jun¹, YANG Xin-Yu¹, CAI Wen², ZHANG Jing-Feng¹, LIANG Xiao-Juan¹

1. College of Chemistry and Materials Engineering, Wenzhou University, Wenzhou 325035, China;
2. College of Materials Science and Engineering, Tongji University, Shanghai 200092, China

Received:2009-11-16 Online:2010-07-10 Published:2010-07-10
Contact: XIANG Wei-Dong. E-mail: weidongxiang@yahoo.com.cn
Supported by:
国家自然科学基金(批准号: 50772075, 50972107)资助.

摘要/Abstract

摘要：

以SbCl₃和L-胱氨酸为反应原料, 采用溶剂热法在170 ℃反应12 h, 制得硫化锑(Sb₂S₃)纳米棒. X射线衍射(XRD)、能量分散光谱(EDS)和X射线光电子能谱(XPS)研究表明所得产物为典型的Sb₂S₃正交结构. 场发射扫描电子显微镜(FESEM)和透射电子显微镜(TEM)研究显示, Sb₂S₃纳米棒长为3~6 μm, 平均直径约为150 nm. 讨论了不同反应时间对Sb₂S₃的形成及其形貌的影响, 并根据实验结果对所合成的一维纳米棒可能的形成机理进行了简单的探讨.

关键词: 硫化锑; 溶剂热; 纳米棒; L-胱氨酸; 生物分子

Abstract:

A simple biomolecule-assisted synthetic route has been successfully developed to prepare antimony sulfide(Sb₂S₃) nanorods at 170 ℃ for 12 h. In this synthetic system, antimony chloride(SbCl₃) is employed to supply antimony source and L-cystine is used as sulfide source. X-ray powder diffraction(XRD), energy dispersion spectroscopy(EDS) and X-ray photoelectron spectroscopy(XPS) results indicate that the as-prepared powder is pure orthorhombic Sb₂S₃. Field-emission scanning electron microscopy(FESEM) and transmission electron microscopy(TEM) show that the Sb₂S₃ nanorods have an average diameter of 150 nm and length ranging from 3 to 6 μm. The effect of reaction time on morphology of the product has been investigated, and a possible formation mechanism for the antimony sulfide nanorods was also discussed.

Key words: Antimony sulfide; Solvothermal; Nanorod; L-cystine; Biomolecule

TrendMD:

钟家松, 向卫东, 刘丽君, 杨昕宇, 蔡文, 张景峰, 梁晓娟. 生物分子辅助溶剂热合成硫化锑纳米棒. 高等学校化学学报, 2010, 31(7): 1303.

ZHONG Jia-Song, XIANG Wei-Dong*, LIU Li-Jun, YANG Xin-Yu, CAI Wen, .... Biomolecule-assisted Solvothermal Synthesis of Sb₂S₃ Nanorods. Chem. J. Chinese Universities, 2010, 31(7): 1303.

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