酞菁氯化铟的固相合成及光敏性能

高等学校化学学报 ›› 2010, Vol. 31 ›› Issue (6): 1167.

酞菁氯化铟的固相合成及光敏性能

谈廷风^1,2, 王世荣¹, 白翔¹, 李祥高¹

1. 天津大学化工学院, 天津 300072;
2. 天津城市建设学院材料科学与工程系, 天津 300384

收稿日期:2009-08-04 出版日期:2010-06-10 发布日期:2010-06-10
通讯作者: 王世荣, 女, 博士, 教授, 主要从事光电功能材料的研究. E-mail: wangshirong@tju.edu.cn
基金资助:
国家“八六三”计划项目(批准号: 2008AA03A315)和天津市应用基础及前沿技术研究计划项目(批准号: 08JCZDJC16900)资助.

Solid Synthesis and Photosensitive Properties of Chloroindium Phthalocyanine

TAN Ting-Feng^1,2, WANG Shi-Rong^1*, BAI Xiang¹, LI Xiang-Gao¹

1. School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China;
2. Department of Materials Science & Engineering, Tianjin Institute of Urban Construction, Tianjin 300384, China

Received:2009-08-04 Online:2010-06-10 Published:2010-06-10
Contact: WANG Shi-Rong. E-mail: wangshirong@tju.edu.cn
Supported by:
国家“八六三”计划项目(批准号: 2008AA03A315)和天津市应用基础及前沿技术研究计划项目(批准号: 08JCZDJC16900)资助.

摘要/Abstract

摘要：

以尿素、邻苯二甲酸酐、钼酸铵和四水合三氯化铟为原料, 乙酸钠为催化剂, 采用固相法合成酞菁氯化铟, 并用元素分析、UV-Vis、IR和XRD进行了表征. 考察了反应物配比、催化剂、反应温度和时间对产率的影响, 寻找出最佳制备条件为n(尿素)∶n(邻苯二甲酸酐)∶n(三氯化铟)=14∶4.5∶1, 以乙酸钠为催化剂, 130 ℃下恒温0.5 h, 在220 ℃下反应4 h后, 用88％(质量分数)浓硫酸提纯. 研究了酞菁氯化铟光敏电阻薄膜的光敏性能, 结果表明, 当用0.2 g酞菁氯化铟和0.6 g PVB制备光敏电阻薄膜时, 分散介质丁酮-环己酮的最佳用量为36 mL, 其电阻灵敏度保持在1.50×10⁸以上, 积分灵敏度保持在30 μA/(lx·V)以上. 研究结果表明, 酞菁氯化铟光敏电阻薄膜具有很好的光敏性能.

关键词: 酞菁氯化铟; 固相合成; 光敏电阻

Abstract:

Metallophthalocyanines are known not only as classical dyes in practical use but also as modern functional materials. However, detailed preparation of chloroindium phthalocyanine wasn′t reported up to the present. In this paper, chloroindium phthalocyanine was synthesized by the solid reaction of urea, phthalic anhydride, molybdic ammonium with hydrated indium trichloride using acetic sodium as catalyzer. The structure was verified by elemental analyst, UV-Vis, IR and XRD. Molar ratio of materials, catalyzer, reaction temperature and reaction time were discussed on the effect of yield of chloroindium phthalocyanine, so the optimal conditions were summarized as follows: n(urea)∶n(phthalic anhydride)∶n(indium trichloride)=14∶4.5∶1, acetic sodium was used as catalyzer. Firstly, reaction mixture was kept at 130 ℃ for 0.5 h, and then the reaction was carried out at 220 ℃ for 4 h. 88% H₂SO₄ was used to purify the product. In addition, the photosensitive properties of photosensitive resistance films were also studied. It was found that when 0.2 g chloroindium phthalocyanine and 0.6 g PVB were used to prepare photosensitive resistance films, the optimal dosage of dispersant butanone-cyclohexanone is 36 mL. The resistance sensitivity and integral ratio sensitivity of the chloroindium phthalocyanine films were over 1.50×10⁸ and 30 μA/(lx·V), respectively. These results show that chloroindium phthalocyanine films have good photosensitive properties.

Key words: Chloroindium phthalocyanine; Solid synthesis; Photosensitive resistance

TrendMD:

谈廷风, 王世荣, 白翔, 李祥高. 酞菁氯化铟的固相合成及光敏性能. 高等学校化学学报, 2010, 31(6): 1167.

TAN Ting-Feng, WANG Shi-Rong*, BAI Xiang, LI Xiang-Gao. Solid Synthesis and Photosensitive Properties of Chloroindium Phthalocyanine. Chem. J. Chinese Universities, 2010, 31(6): 1167.

参考文献

[1]HUANG De-Yin(黄德音), YAN Yi-Long(晏意隆). Sensitive Materials(感光材料)[J], 1997, 1: 9—12
[2]ZHENG Wei-Tao(郑伟涛). Pellicular Materials and Technics(薄膜材料与薄膜技术)[M], Beijing: Chemical Industrial Press, 2003: 69—73
[3]SHEN Yong-Jia(沈永嘉). Synthesis and Application of Phthalocyanine(酞菁合成和应用)[M], Beijing: Chemical Industrial Press, 2000: 23—28
[4]Yu S. K., Ma C. Y., Cheng C. H., Wang X., Ji D. M., Fan Z. Q., Xia D. C., He W., Chang Y. C., Du G. T.. Dyes and Pigments[J], 2008, 76: 492—498
[5]Chauke V., Durmus M., Nyokong T.. Journal of Photochemistry and Photobiology A-Chemistry[J], 2007, 192: 179—187
[6]Chen Y., Hanack M., Araki Y., Ito O.. Chem. Soc. Rev.[J], 2005, 34: 517—531
[7]DENG Jian-Cheng(邓建成), DENG Xiao-Qin(邓晓琴). Journal of Xiangtan University(湘潭大学学报)[J], 1999, 21(4): 58—61
[8]YIN Huan-Shun(殷焕顺), DENG Jian-Cheng(邓建成), ZHOU Yan(周燕). Dyes and Dyeing(染料与染色)[J], 2004, 3(41): 150—152
[9]XIA Dao-Cheng(夏道成), YU Shu-Kun(于书坤), MA Chun-Yu(马春雨), CHENG Chuan-Hui(程传辉), GUO Zhen-Qiang(郭振强), JI Dong-Mei(纪冬梅), FAN Zhao-Qi(范昭奇), DU Xi-Guang(杜锡光), WANG Xu(王旭), DU Guo-Tong(杜国同). Chem. J. Chinese Universities(高等学校化学学报)[J], 2008, 29(2): 244一246
[10]Ma C. Y., Ye K. Q., Yu S. K., Du G. T., Zhao Y. F., Cong F. D., Chang Y. C., Jiang W. H., Cheng C. H., Fan Z. Q., Yu H. F., Li W. C.. Dyes and Pigments[J], 2007, 74: 141—147
[11]HUANG Zi-Yang(黄紫洋), XUE Jin-Ping(薛金萍), CHEN Jin-Can(陈锦灿), CHEN Nai-Sheng(陈耐生), HUANG Jin-Ling(黄金陵). Chem. J. Chinese Universities(高等学校化学学报)[J], 2008, 29(3): 445—448
[12]CHEN Jin-Can(陈锦灿), CHEN Hong-Wei(陈宏炜), LI Yong-Dong(李永东), WANG Jun-Dong(王俊东), CHEN Nai-Sheng(陈耐生), HUANG Jin-Ling(黄金陵), HUANG Ming-Dong(黄明东). Chem. J. Chinese Universities(高等学校化学学报)[J], 2008, 29(11): 2131—2137
[13]LIU Ying(刘莹), CHEN Yu(陈彧), FENG Miao(冯苗), LIN Ying(林楹), Doyle J. J., Blau W. J., CAI Liang-Zhen(蔡良珍). Chem. J. Chinese Universities(高等学校化学学报)[J], 2007, 28(11): 2092—2095
[14]Nakamura K.. J. Electrochem. Soc.[J], 1985, 132: 1757—1762
[15]Campbell D.. Thin Film Technology[M], New York: Mc Graw, 1970: 155—168
[16]Ye J., Chen H. Z., Wang M.. J. Mater. Sci.[J], 2003, 38: 4021—4025
[17]Moser F. H., Thomos A. L.. The Phthalocyanines[M], BocaRaton: CRC Press, 1983
[18]Wasielewski M. R.. Chem. Rev.[J], 1992, 92: 435—452
[19]Naper A., Collins R. A.. Phys. Stat. Sol.(a)[J], 1994, 91(144): 91—104
[20]TANG Ning-Li(唐宁莉), PENG De-Xian(彭德贤), FAN Hui-Qin(范会钦). Journal of Guilin Institute of Technology(桂林工学院学报)[J], 1994, 14(2): 188—192
[21]Kobayash T.. Spectrochimica. Acta[J], 1970, 26A: 1305—1311
[22]HUANG Jin-Ling(黄金陵), PENG Yi-Ru(彭亦如). Spectroscopy and Spectral Analysis(光谱学与光谱分析)[J], 2001, 21(1): 1—6