孪生球状碳酸钙的直接混合沉淀法制备及表征

高等学校化学学报 ›› 2010, Vol. 31 ›› Issue (10): 1940.

孪生球状碳酸钙的直接混合沉淀法制备及表征

陈先勇1, 唐琴1, 胡卫兵1, 但悠梦1, 周贵云2

1. 湖北民族学院化学与环境工程学院, 恩施 445000;
2. 四川大学化工学院, 成都 610065

收稿日期:2010-02-05 出版日期:2010-10-10 发布日期:2010-10-10
通讯作者: 陈先勇, 男, 副教授, 主要从事超细粉体的开发应用研究. E-mail: chen_xianyong@163.com
基金资助:
国家自然科学基金(批准号: 20871044)、湖北省教育厅项目(批准号: B200729005)和湖北恩施州科技局重点项目(批准号: 2009A33)资助.

Preparation and Characterization of Twin Spherical Calcium Carbonate by the Direct Mixing Precipitation Method

CHEN Xian-Yong1*, TANG Qin1, HU Wei-Bing1, DAN You-Meng1, ZHOU Gui-Yun2

1. Department of Chemical and Environmental Engineering, Hubei University for Nationalities, Enshi 445000, China;
2. Institute of Chemical Engineering, Sichuan University, Chengdu 610065, China

Received:2010-02-05 Online:2010-10-10 Published:2010-10-10
Contact: CHEN Xian-Yong. E-mail: chen_xianyong@163.com
Supported by:
国家自然科学基金(批准号: 20871044)、湖北省教育厅项目(批准号: B200729005)和湖北恩施州科技局重点项目(批准号: 2009A33)资助.

摘要/Abstract

摘要： 以醋酸钙和碳酸钠为原料, 柠檬酸三钠为晶形控制剂, 利用液相直接混合沉淀法合成了分散性好、粒度约1.5~3.0 μm、长短轴比约2∶1的孪生球形碳酸钙晶体. 利用扫描电子显微镜(SEM)、X射线衍射仪(XRD)、傅里叶红外光谱仪(FTIR)、原子力扫描探针显微镜(ASPM)和粒度分析仪等对样品进行了表征. 结果表明, 在不添加柠檬酸三钠的溶液中得到微米级的立方状碳酸钙晶体, 而添加柠檬酸三钠(质量分数30%~40%)后则得到具有不同表面粗糙度的孪生球状碳酸钙晶体. 同时, 用分形生长理论和成核限制聚集(NLA)模型对孪生球状碳酸钙粒子的形成机理进行了分析.

关键词: 孪生球状结构, 碳酸钙, 直接混合沉淀法, 柠檬酸三钠

Abstract: The well dispersed twin spherical CaCO3 particles with granular size of 1.5—3.0 μm and a ratio of length to brachyaxis about 2∶1 were prepared directly via a liquid mixing precipitation method in the presence of trisodium citrate, using calcium acetate and sodium calcium solution as raw materials. The obtained CaCO3 samples were characterized by means of scanning electron microscope(SEM), X-ray diffraction(XRD), Fourier transform infrared spectroscopy(FTIR), thermogravimety analysis(TG), atomic force scanning probe microscopy(ASPM) and size analysis. The results show that twin spherical CaCO3 particles with different crude surface degree are obtained in the presence of mass fraction of trisodium citrate 30%~40%, whereas, only cubic micron CaC03 crystals are obtained without trisodium citrate. The formation mechanism of twin spherical CaCO3 was analyzed by the fractal growth theory and the nucleation limited aggregation(NLA) model at the same time.

Key words: Twin structure ball-like, Calcium carbonate, Direct mixing precipitation method, Trisodium citrate

TrendMD:

陈先勇, 唐琴, 胡卫兵, 但悠梦, 周贵云. 孪生球状碳酸钙的直接混合沉淀法制备及表征. 高等学校化学学报, 2010, 31(10): 1940.

CHEN Xian-Yong*, TANG Qin, HU Wei-Bing, DAN You-Meng, ZHOU Gui-Yun. Preparation and Characterization of Twin Spherical Calcium Carbonate by the Direct Mixing Precipitation Method. Chem. J. Chinese Universities, 2010, 31(10): 1940.

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