聚醚链段长度对氨基聚醚-环氧树脂力学性能的影响

高等学校化学学报 ›› 2009, Vol. 30 ›› Issue (7): 1454.

聚醚链段长度对氨基聚醚-环氧树脂力学性能的影响

赵立英, 马会茹, 官建国

武汉理工大学材料复合新技术国家重点实验室, 武汉 430070

收稿日期:2008-11-20 出版日期:2009-07-10 发布日期:2009-07-10
通讯作者: 官建国, 男, 博士, 教授, 主要从事聚合物及纳米复合材料研究. E-mail: guanjg@whut.edu.cn
基金资助:
国家“八六三”计划(批准号: 2006AA03A209)、国防基础科研项目(批准号: D1420061057)和教育部新世纪优秀人才支持计划(批准号: NCET-05-0660)资助.

Influence of Polyether Segment Length on Mechanical Properties of Cured Epoxy Resins Based on Amino-terminated Poly(ethylene glycol) and Diglycidyl Ether of Bisphenol

ZHAO Li-Ying, MA Hui-Ru, GUAN Jian-Guo*

State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan 430070, China

Received:2008-11-20 Online:2009-07-10 Published:2009-07-10
Contact: GUAN Jian-Guo. E-mail: guanjg@whut.edu.cn
Supported by:
国家“八六三”计划(批准号: 2006AA03A209)、国防基础科研项目(批准号: D1420061057)和教育部新世纪优秀人才支持计划(批准号: NCET-05-0660)资助.

摘要/Abstract

摘要：

以柔性端氨基聚醚(BATPE)和双酚A环氧树脂(DGEBA)为原料, 制备了无微相分离结构的无定型AB交联热固性树脂. 测试了3种不同聚乙二醇(PEG)链段长度(M_PE)的BATPE-DGEBA环氧树脂固化产物的应力-应变曲线、动态力学温度谱和冲击断面形貌. 结果表明, 在环氧树脂交联网络中引入两端与DGEBA化学连接的PEG链段能避免微相分离结构的生成, 有利于提高DGEBA链段的应变松弛速率. 增加M_PE, 一方面能降低环氧树脂固化产物的玻璃化转变温度和室温下的刚度和拉伸强度, 增加韧性(包括冲击强度和拉伸韧性)、断裂应变和模量损耗因子; 另一方面也能提高固化产物在低温下的储存模量. 优化M_PE可制备出在中低温下同时具有优异的拉伸强度、模量、断裂应变和冲击性能的BATPE-DGEBA环氧树脂.

关键词: 环氧树脂; 端氨基聚醚; 微相分离; 力学性能; 动态力学温度谱

Abstract:

An advanced amorphous AB-type thermosetting resin without nanophase separation was synthesized via directly moulding diglycidyl ether of bisphenol A(DGEBA) and α,ω-bisaminophenyl terminated poly(ethylene glycol)(BATPE). The stress-strain curve, dynamic mechanical thermal analysis and morphologies of impact fracture surfaces of the cured products were investigated as functions of flexible poly(ethylene glycol) segment length(M_PE). The results show that the homogeneous epoxy resin without nanophase separation are available by incorporating poly(ethylene glycol) segments into epoxy crosslinked networks via chemically linked with DGEBA at both terminals, beneficial for increasing free volume fractions and strain relax rates. When M_PE is extended, the glass transition temperature, the room-temperature Young′s modulus and tensile strength of the cured products decrease while toughness, elongation and modulus loss factors increase. The elastic mo-dulus of the cured products at low temperature(i.e. -40 ℃) enhances with increasing M_PE. Consequently, thermosetting epoxy resins based on BATPE-DGEBA which exhibits excellent tensile strength, modulus and impact strength at moderate and low temperature are obtained by facile optimization of M_PE.

Key words: Epoxy resin; Amine-terminated polyether; Nanophase separation; Mechanical property; Dynamic mechanical thermal analysis

TrendMD:

赵立英, 马会茹, 官建国. 聚醚链段长度对氨基聚醚-环氧树脂力学性能的影响. 高等学校化学学报, 2009, 30(7): 1454.

ZHAO Li-Ying, MA Hui-Ru, GUAN Jian-Guo*. Influence of Polyether Segment Length on Mechanical Properties of Cured Epoxy Resins Based on Amino-terminated Poly(ethylene glycol) and Diglycidyl Ether of Bisphenol. Chem. J. Chinese Universities, 2009, 30(7): 1454.

参考文献

[1]Guo Q. P.. Polymer[J], 1995, 36(25): 4753—4760
[2]Tan C. B., Sun H., Fung B. M., et al.. Macromol.[J], 2000, 33(17): 6249—6254
[3]Nakamura Y., Yamaguchi M., Okubo M., et al.. Polymer[J], 1991, 32(16): 2976—2979
[4]Lee J., Yee A. F.. Polymer[J], 2001, 42(2): 589—597
[5]Jansen B. J. P., Rastogi S., Meijer H. E. H., et al.. Macromol.[J], 1999, 32(19): 6290—6297
[6]Ratna D.. Polymer[J], 2001, 42(9): 4209—4218
[7]Frigione M. E., Mascia L., Acierno D.. Eur. Polym. J.[J], 1995, 31(11): 1021—1029
[8]Dean K., Cook W. D.. Macromol.[J], 2002, 35(21): 7942—7954
[9]Zhang B. L., Tang G. L., Shi K. Y., et al.. J. Appl. Polym. Sci.[J], 1999, 71(1): 177—184
[10]CHANG Peng-Shan(常鹏善), ZUO Rui-Lin(左瑞霖), WANG Ru-Min(王汝敏), et al.. Acta Polymerica Sinica(高分子学报)[J], 2002, (5): 682—684
[11]Thio Y. S., Wu J. X., Bates F. S.. Macromol.[J], 2006, 39(21): 7187—7189
[12]Dean J. M., Verghese N. E., Pham H. Q., et al.. Macromol.[J], 2003, 36(25): 9267—9270
[13]Liu J., Sue H. J., Thompson Z. J., et al.. Macromol.[J], 2008, 41(20): 7616—7624
[14]Ruiz-Pérez L., Royston G. J., Fairclough J. P. A., et al.. Polymer[J], 2008, 49(21): 4475—4488
[15]Balakrishnan S., Start P. R., Raghavan D., et al.. Polymer[J], 2005, 46(25): 11255—11262
[16]SUN Tao(孙涛), GUAN Jian-Guo(官建国), YU Jian-Ying(余剑英), et al.. Polymer Materials Science and Engineering(高分子材料科学与工程)[J], 2005, 21(1): 117—120
[17]Yang G., Fu S. Y., Yang J. P.. Polymer[J], 2007, 48(1): 302—310
[18]Samanta B. C., Maity T., Dalai S., et al.. J. Adhes. Sci. Technol.[J], 2006, 20(6): 491—502
[19]Guan J. G., Yuan R. Z., Xie H. Q.. Polymer[J], 1998, 39(22): 5307—5314
[20]Ma H. R., Guan J. G., Yuan R. Z.. Int. J. Mod. Phys. B[J], 2007, 21(28/29): 4961—4966
[21]Robeson L. M., Hale W. F., Merriam C. N.. Macromol.[J], 1981, 14(6): 1644—1650
[22]GUAN Jian-Guo(官建国), MA Hui-Ru(马会茹), ZHAO Li-Ying(赵立英), et al.. Preparation of α,w-Bisaminophenyl Terminated Poly(ethylene glycol) Used as Curing Agent for Epoxy Resin(用作环氧树脂固化剂的α,w-端氨基聚醚及其制备方法)[P], CN1803882, 2006
[23]Hillmyer M. A., Lipic P. M., Hajduk D. A., et al.. J. Am. Chem. Soc.[J], 1997, 119(11): 2749—2750
[24]Lipic P. M., Bates F. S., Hillmyer M. A.. J. Am. Chem. Soc.[J], 1998, 120(35): 8963—8970
[25]Jansen B. J. P., Rastogi S., Meijer H. E. H., et al.. Macromol.[J], 2001, 34(12): 3998—4006