二茂钛取代邻苯二甲酸配合物的合成及其电场响应性能

高等学校化学学报 ›› 2009, Vol. 30 ›› Issue (5): 855.

二茂钛取代邻苯二甲酸配合物的合成及其电场响应性能

何玲, 高玲香, 高子伟, 张莹, 吴晓妮, 倪迎瑞

陕西师范大学化学与材料科学学院, 应用表面与胶体化学教育部重点实验室, 西安 710062

收稿日期:2008-09-27 出版日期:2009-05-10 发布日期:2009-05-10
通讯作者: 高玲香, 女, 副教授, 主要从事金属有机配合物和智能材料研究, E-mail: gaolx@snnu.edu.cn
基金资助:
国家自然科学基金(批准号:20771071, 20941001), 教育部“新世纪优秀人才支持计划”项目和陕西省自然科学基金(批准号: 2007B06, 2006B23)资助.

Synthesis and Electric Field Response Behavior of 4-Chlorophthalate Titanocene Complexes

HE Ling, GAO Ling-Xiang*, Gao Zi-Wei, ZHANG Ying, WU Xiao-Ni, NI Ying-Rui

Key Lab of Applied Surface and Colloid Chemistry of MOE, School of Chemistry and Materials Science, Shaanxi Normal University, Xi′an 710062, China

Received:2008-09-27 Online:2009-05-10 Published:2009-05-10

摘要/Abstract

摘要：

分别采用水相法和两相法简便合成了两种4-氯代邻苯二甲酸二茂钛配合物, 并用IR, ¹H NMR, TG, EA及SEM等手段对产物的结构和形貌进行了表征. 分析了反应条件对产物粒径和形貌的影响, 研究了茂钛配合物在含水复合弹性体介质中对电场作用的响应性能. 结果表明, 两种方法所得配合物的结构有所不同, 水相法所得配合物中羧基氧以单齿形式与钛(Ⅳ)配位, 而两相法中羧基氧则以双齿形式与钛(Ⅳ)配位. 在不同条件下获得的两种配合物均聚集为空心微球, 粒径分别为05~1 μm 和 2~5 μm. 它们都具有较强的电场响应性能, 且该性能与分子结构和微球表面润湿性相关.

关键词: 茂钛配合物, 4-氯代邻苯二甲酸, 空心微球, 电场响应性能

Abstract:

4-Chlorophthalate titanocene complexes were synthesized by reacting Cp₂TiCl₂ with 4-chlorophthalic acid in water or in CHCl₃/H₂O medium. The complexes were characterized by TG, IR, ¹H NMR, SEM and EA. The effects of reactive condition on the particle size and the morphology of complexes were investigated. In addition, the electric field response performance of titanocene complexes which were dispersed in the glycerin/gelatin aqueous elastomers were also studied. It was found that there are differences in the structure of the complexes which were synthesized by different methods. The hollow microspheres of complexes with diameter of 05—1 μm and 2—5 μm were obtained by aqueous phase method and two-phase method, respectively. Both of the complexes have obvious response to electric field.

Key words: Titanocene complex, 4-Chlorophthalic acid, Hollow microsphere, Electric field response performance

TrendMD:

何玲, 高玲香, 高子伟, 张莹, 吴晓妮, 倪迎瑞. 二茂钛取代邻苯二甲酸配合物的合成及其电场响应性能. 高等学校化学学报, 2009, 30(5): 855.

HE Ling, GAO Ling-Xiang*, Gao Zi-Wei, ZHANG Ying, WU Xiao-Ni, NI Ying-Rui. Synthesis and Electric Field Response Behavior of 4-Chlorophthalate Titanocene Complexes. Chem. J. Chinese Universities, 2009, 30(5): 855.

参考文献

Potter G. D., Baird M. C., Cole S. P. C.. J. Organomet. Chem.[J], 2007, 692: 3508—3518
Benjamin A. C., Frey A. S. P., Gardine M. G. R., et al.. J. Organomet. Chem.[J], 2008, 693: 776—780
Liu F. C., Chen J. H., Chen S. C., et al.. J. Organomet. Chem.[J], 2005, 690: 291—300
Skompska M., Vorotyntsev M. A., Goux J., et al.. Electrochim. Acta[J], 2008, 53: 3844—3853
Skompska M., Vorotyntsev M. A., Refczynska M., et al.. Electrochim. Acta[J], 2006, 51: 2108—2119
Alt H. G., Licht E. H., Licht A. I., et al.. Coord. Chem. Rev.[J], 2006, 250: 2—17
Hong Y., Mun S.-D., Lee J., et al.. J. Organomet. Chem.[J], 2008, 693: 1945—1951
Zhang H., Katao S., Nomura K., et al.. J. Organometallics[J], 2007, 26(24): 5967—5977
CAI Zheng-Hong(蔡正洪), TANG Jing(唐静), TANG Yu(唐瑜), et al.. Chem. J. Chinese Universities(高等学校化学学报)[J], 2005, 26(6): 1021—1023
Schlichte K., Kratzke T., Kaskel S.. Microporous and Mesoporous Materials[J], 2004, 73: 81—88
Müller U., Hesse M., Yaghi O. M., et al.. Process for the Epoxidation of an Organic Compound with Oxygen or an Oxygen-delivering Compounds Using Catalysts Containing Metal-organic Frame-work Materials, US 6624318B1[P], 2003
Wang Q. M., Shen D., Bülow M., et al.. Microporous and Mesoporous Materials[J], 2002, 55: 217 —230
Xu H. B., Su Z. M., Shao K. Z., et al.. Inorganic Chemistry Communications[J], 2004, 7: 260—263
Pan J. H., Zhang X., Du A. J., et al.. J. Am. Chem. Soc.[J], 2008, 130(34): 11256—11257
Ren M. M., Zhou Z., Gao X. P., et al.. J. Phys. Chem. C[J], 2008, 112(33): 13043—13046
ZHANG You-Wei(张幼维), ZHAO Jiong-Xin(赵炯心), JIANG Ming(江明), et al.. Chem. J. Chinese Universities(高等学校化学学报)[J], 2006, 27(9): 1762—1766
Peng X., Zhang L.. Langmuir[J], 2005, 21(3): 1091—1095
Caruso R. A., Susha A., Caruso F.. Chem. Mater.[J], 2001, 13(2): 400—409
Lu L., Eychmüller A.. Acc. Chem. Res.[J], 2008, 41(2): 244—253
Sakanishi K., Hasuo H., Kishino M., et al.. Energy & Fuels[J], 1996, 10(1): 216—219
Yaghi O. M., Davis C. E., Li G., et al.. J. Am. Chem. Soc.[J], 1997, 119: 2861—2868
WU Shao-Zu(吴绍祖), ZHOU Yao-Kun(周耀坤). J. Lanzhou Univ.( Nat. Sci. Ed.)[兰州大学学报(自然科学版)[J], 1982, 18(3): 57—63
GAO Ling-Xiang(高玲香), GAO Zi-Wei(高子伟). Acta Chimnca Sinica(化学学报)[J], 2002, 60: 904—909
Gao L. X., Zhao X. P.. Journal of Applied Polymer Science[J], 2004, 94: 2517—2521
Cutler A., Raja M., Todaro A.. Inorg. Chem.[J], 1987, 26: 2877—2881
Tian L. J., Qian B. C., Sun Y. X.. Appl. Organometal. Chem.[J], 2005, 19: 980—987
Piszczek P., Richert M., Wojtczak A.. Polyhedron[J], 2008, 27: 602—608
Nakamoto K.. Infrared and Raman Spectra of Inorganic and Coordination Compounds[M], New York: Wiley-VCH, 1997
SUN Ping(孙平). Study on Synthesis and Reaction of Mono and Hetero Nucleus Titanocene Complexes in Mild Condition(温和条件下单核、异核茂钛配合物的合成及反应研究)[D], Xi′an: Shaanxi Normal University, 2005: 50—51
SHEN Zhong(沈钟), WANG Guo-Ting(王果庭). Colloid and Surface Chemistry(胶体与表面化学)[M], Beijing: Chemical Industry Press, 1991: 316
Luo Y. Y., Duan G. T., Ye M., et al.. J. Phys. Chem. C[J], 2008, 112: 2349—2352
Wang B. X., Zhao Y., Zhao X. P.. Colloids and Surfaces A: Physicochem. Eng. Aspects[J], 2007, 295: 27—33

[1]	佟永纯, 王清云, 白庆玲, 李振, 贾传明. 双重Pickering乳液模板法制备无机-有机复合空心微球[J]. 高等学校化学学报, 2018, 39(7): 1462.
[2]	任志宇, 李忠涛, 杜世超, 吴君, 孔令俊, 付宏刚. Ag/mSiO₂空心微球的制备及SERS标记性能[J]. 高等学校化学学报, 2014, 35(7): 1541.
[3]	王金刚, 姬平利, 孔祥正. 共沉淀法制备Ag/AgCl-TiO₂空心复合纳米微球及其光催化性能[J]. 高等学校化学学报, 2013, 34(11): 2635.
[4]	吴晓妮, 高玲香, 刘毅, 高子伟, 裴挫萍, 高淑娟. 形貌可控钛酸锶钡的制备及其电场响应性能[J]. 高等学校化学学报, 2009, 30(6): 1066.
[5]	邓字巍, 陈敏, 周树学, 游波, 武利民 . 一种制备单分散SiO₂空心微球的新方法[J]. 高等学校化学学报, 2006, 27(10): 1795.
[6]	范荫恒, 廖世健, 徐筠, 钱廷龙, 黄吉玲. 茂钛配合物-纳米氢化钠双组分高活性加氢催化剂的研究[J]. 高等学校化学学报, 1997, 18(10): 1683.