共溶剂对ZnO多孔纳米块体孔径均匀性的影响

高等学校化学学报 ›› 2006, Vol. 27 ›› Issue (3): 414.

共溶剂对ZnO多孔纳米块体孔径均匀性的影响

李梅¹,孙海燕^1,2,刘秀琳³,徐红燕¹,王成建²,崔得良¹,蒋民华¹

1. 山东大学晶体材料国家重点实验室,2. 山东大学物理与微电子学院,济南 250100;
3. 中国民航学院理学院,天津 300300

收稿日期:2005-05-19 出版日期:2006-03-10 发布日期:2006-03-10
通讯作者: 崔得良(1965年出生),男,博士,教授,博士生导师. 主要从事多孔纳米材料研究. E-mail: cuidl@sdu.edu.cn
基金资助:
国家自然科学基金(批准号： 50272036,20473048和90206042)、教育部科学技术研究重大项目、重点项目以及博士学科点基金的资助.

Effects of Co-solvent on the Uniformity of Pore Size of ZnO Bulk Porous Nanosolids

LI Mei¹,SUN Hai-Yan^1,2,LIU Xiu-Lin¹,XU Hong-Yan¹,WANG Cheng-Jian²,CUI De-Liang^1*,JIANG Min-Hua¹

1. State Key Lab of Crystal Materials Shandong University,Jinan 250100,China;
2. School of Physics & Microelectronics,Shandong University,Jinan 250100,China;
3. College of Science,Civil Aviation University of China,Tianjin 300300,China

Received:2005-05-19 Online:2006-03-10 Published:2006-03-10

摘要/Abstract

摘要：

以十二烷基硫酸钠(SDS)的水溶液为造孔剂,用溶剂热压方法制备了大孔径的ZnO多孔纳米块体,并进一步考察了添加聚乙二醇400(PEG-400)对样品中孔道的影响. 实验发现,向十二烷基硫酸钠(SDS)的水溶液中加入聚乙二醇400组成共溶剂后, 制备的ZnO多孔纳米块体的孔径大幅度减小,比表面积和孔隙率也明显降低,但孔径的均匀性显著提高.

关键词: ZnO纳米颗粒; 多孔纳米块体; 溶剂热压方法; 共溶剂

Abstract:

Using sodium dodecylsulfate solution(SDS) as the pore-forming agent and ZnO nanoparticles as the starting material,ZnO porous bulk solid was successfully prepared by a novel solvothermal hot press method. Furthermore,the effects of the addition of polyethylene glycol 400(PEG-400) into the solvent were also investigated. It was found that,the pore diameter of the ZnO porous bulk solids largely decreased when PEG-400 was added into the solvent. Besides,the specific surface area and porosity also decrease correspondingly. On the other hand,the uniformity of the channel diameter of ZnO bulk porous nanosolids was greatly improved.

Key words: ZnO nanoparticle; ZnO bulk porous nanosolid; Solvothermal hot press; Co-solvent

中图分类号:

O614.24⁺1

TrendMD:

李梅孙海燕刘秀琳徐红燕王成建崔得良蒋民华. 共溶剂对ZnO多孔纳米块体孔径均匀性的影响. 高等学校化学学报, 2006, 27(3): 414.

LI Mei, SUN Hai-Yan, LIU Xiu-Lin, XU Gong-Yan, WANG Cheng-Jian, CUI De-Liang, JIANG Min-Hua. Effects of Co-solvent on the Uniformity of Pore Size of ZnO Bulk Porous Nanosolids. Chem. J. Chinese Universities, 2006, 27(3): 414.