相转移催化应用于催化裂化汽油氧化脱硫的研究

高等学校化学学报 ›› 2006, Vol. 27 ›› Issue (1): 144.

相转移催化应用于催化裂化汽油氧化脱硫的研究

赵地顺, 马四国, 刘翠微, 任红威

河北科技大学化学与制药工程学院, 石家庄 050018

收稿日期:2005-09-06 出版日期:2006-01-10 发布日期:2006-01-10
通讯作者: 赵地顺(1945年出生)，男，教授，博士生导师，主要从事清洁能源化工研究. E-mail: zhao_dsh@hebust.edu.cn
基金资助:
国家自然科学基金(批准号： 20276015)资助

Studies on Desulfurization from Cracking of Gasoline
Catalyzed by Phase Transfer Catalyst

ZHAO Di-Shun, MA Si-Guo, LIU Cui-Wei, REN Hong-Wei

College of Chemistry and Pharmaceutical Engineering, Hebei University of Science and
Technology, Shijiazhuang 050018, China

Received:2005-09-06 Online:2006-01-10 Published:2006-01-10
Contact: ZHAO Di-Shun，E-mail: zhao_dsh@hebust.edu.cn

摘要/Abstract

摘要：

随着人们环境保护意识的增强及原油硫含量的增大, 生产满足环境保护要求的清洁燃料是全球炼油工业的发展趋势, 燃料油脱硫显得越来越重要. 在众多的脱硫方法中, 选择性氧化脱硫技术以其工艺条件温和, 脱硫效果明显等特点, 受到了炼油行业的极大关注^[1~3], 但脱硫率偏低(30％), 其关键是水相氧化剂与含硫化合物的有效混合. 本文将相转移催化应用于催化裂化(FCC)汽油的氧化脱硫中, 并对脱硫的工艺和机理进行了研究.

关键词: 关键词相转移; 氧化; 脱硫; 汽油

Abstract:

AbstractDesulfurization from cracking of gasoline via selective oxidation catalyzed by phase tranfer catalyst is investigated. Using cetyltrimethyl ammonium bromide(CTAB) as the phase transfer catalyst, hydrogen peroxide as the oxidant, acetic anhydride as the assistant oxidant, the effects of different conditions, such as reaction time, reaction temperature, the content of phase transfer catalyst, on the desulfurization rate are investigated. When the volume ratio of gasoline and oxidative system is 0.2, the volume ratio of hydrogen peroxide and acetic anhydride is 5, the content of phase transfer catalysis is 0.06 g, reaction time is 0.5 h, the desulfurization rate of the FCC gasoline is 80.13%. After analyzed by GC-FPD, there is no oxidized sulfur-containing compounds remained in the gasoline.

中图分类号:

TrendMD:

赵地顺马四国刘翠微任红威. 相转移催化应用于催化裂化汽油氧化脱硫的研究. 高等学校化学学报, 2006, 27(1): 144.

DIAO Di-Shun, MA Si-Guo, LIU Cui-Wei, REN Hong-Wei. Studies on Desulfurization from Cracking of Gasoline
Catalyzed by Phase Transfer Catalyst. Chem. J. Chinese Universities, 2006, 27(1): 144.