高等学校化学学报

高等学校化学学报 ›› 2005, Vol. 26 ›› Issue (4): 710.

• 研究论文 • 上一篇    下一篇

Pd微电极阵列表面纳米薄膜的方波电位制备及其特殊的红外性能

李君涛, 陈友江, 苏章菲, 周志有, 陈声培, 孙世刚   

  1. 厦门大学化学系, 固体表面物理化学国家重点实验室, 厦门 361005
  • 收稿日期:2004-05-18 出版日期:2005-04-10 发布日期:2005-04-10
  • 通讯作者: 孙世刚(1954年出生),男,博士,教授,博士生导师,主要从事表面电化学与电催化研究.E-mail:sgsun@xmu.edu.cn E-mail:sgsun@xmu.edu.cn
  • 基金资助:

    国家自然科学基金(批准号:90206039,20021002);国家“九七三”计划项目(批准号:2002CB211804)资助.

Preparation of Nanostructured Films on Surface of Pd Microelectrode Array by Square Wave Potential and Their Anomalous IR Properties

LI Jun-Tao, CHEN You-Jiang, SU Zhang-Fei, ZOU Zhi-You, CHEN Sheng-Pei, SUN Shi-Gang   

  1. State Key Laboratory of Physical Chemistry of Solid Surfaces, Department of Chemistry, Xiamen University, Xiamen 361005, China
  • Received:2004-05-18 Online:2005-04-10 Published:2005-04-10

PDF (PC)

被引次数

15

摘要： 制备了单根可寻址Pd微电极阵列,运用方波电位法对阵列上每根Pd微电极处理不同时间,诱导生成一系列不同纳米结构的Pd薄膜.以CO为探针分子,结合原位显微傅里叶变换红外反射光谱进行表面组合电化学研究,一次性地获得CO吸附在不同纳米结构Pd薄膜上的红外光谱.观察到随方波电位法处理时间的逐步增加,桥式吸附态CO的红外光谱峰从正常吸收光谱到类Fano光谱,再到异常红外光谱的转变过程.结合扫描电子显微镜观察纳米薄膜的形貌,发现不同红外光谱特征都对应着特定的纳米结构.

关键词: Pd微电极阵列, 纳米薄膜, 原位显微FTIR, 表面组合电化学, 异常红外效应

Abstract: An individually addressable array of Pd microelectrodes was combined with in situ microscope FTIR reflection spectroscopy in the current paper to carry out surface combinatorial studies. Pd film of different nanostructures on the array was prepared electrochemically by applying the method of square wave potential. The electrochemical behavior and surface structure of the Pd film were investigated respectively by using cyclic voltammetry and scanning electron microscopy. It revealed that, through the surface combinatorial studies, with the increase of treatment time of the square wave potential, the spectral IR characteristics of bridge bonded CO on the array was transformed successively from normal absorption band to Fano-like spectral line shape, and finally to abnormal IR features. The results demonstrate that the anomalous IR properties of Pd thin film depend strongly on the nanostructure of the film.

Key words: Pd microelectrodes array, Nanostructured films, In situ microscope FTIR spectroscopy, Surface combinatorial electrochemistry, Abnormal infrared effects

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