高等学校化学学报

高等学校化学学报 ›› 2005, Vol. 26 ›› Issue (1): 146.

• 研究快报 • 上一篇    下一篇

相转移催化合成酯基取代酞菁铜及其光导性能

王泳, 陈红征, 汪茫   

  1. 浙江大学高分子科学与工程系, 硅材料国家重点实验室, 杭州 310027
  • 收稿日期:2004-10-10 出版日期:2005-01-10 发布日期:2005-01-10
  • 通讯作者: 汪茫(1938年出生),男,教授,主要从事有机半导体材料性能研究.E-mail:mwang@zju.edu.cn E-mail:mwang@zju.edu.cn
  • 基金资助:

    国家自然科学基金(批准号:90201009,50225312,50433020)资助

Synthesis of Ester Substituted Copper Phthalocyanines by Phase Transfer Catalysis Reaction and Their Photoconductivity

WANG Yong, CHEN Hong-Zheng, WANG Mang   

  1. State Key Lab of Silicon Materials, Department of Polymer Science and Engineering, Zhejiang University, Hangzhou 310027, China
  • Received:2004-10-10 Online:2005-01-10 Published:2005-01-10

PDF (PC)

被引次数

22

关键词: 酯基取代酞菁铜, 相转移催化反应, 光导性能

Abstract: Copper-tetra-4-(butyloxycarbonyl) phthalocyanine, copper-tetra-4-(octyloxycarbonyl) phthalocyanine and copper-tetra-4-(dodecoxycarboxyl) phthalocyanine were synthesized by the phase transfer catalysis reaction. The reaction has several advantages in comparison with the previous carboxyl-esterified method, such as the milder conditions, the shorter reaction time(3—6 h), the higher yield(>95%), and so on. Because of the difference in the substituent group length of these compounds, the morphology and the congregation of the molecules in their casting films is different, leading to the different photoconductivities of them.

Key words: Ester substituted copper phthalocyanines, Phase transfer catalysis reaction, Photoconductivity

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